The organization of the water-chemistry regime in the loop of a passive safety system, whose purpose is emergency removal of heat from the core of a nuclear power reactor, is examined. It is shown that a selfregulated water-chemistry regime in which gaseous products of radiolysis can be dissolved in water coolant and recirculated into the irradiation zone, which will intensify liquid-phase radiation-chemical reactions of hydrogen with oxygen and organic release of gases from the liquid phase into the vapor-gas phase of the coolant, can arise in the loop of a passive safety system. This will result in the establishment in the loop of dynamic equilibrium between the release and dissolution of gases and will enable prolonged functioning of the safety system without intervention from the outside. The physicochemical and technical criteria for the appearance of a self-regulated water-chemistry regime for closed loops with natural circulation of the two-phase coolant are formulated and substantiated.A passive cool-down system is a promising solution for increasing the safety of the first loop of a nuclear power facility [1]. It must remain serviceable during a prolonged period of time not only without the intervention of plant workers but also in the absence of electricity. Independence of operation from energy input and protection from failures of active components can be attained by implementing the principle of internal self-protection -the use of natural processes, specifically, natural circulation of the coolant and self-regulated water-chemistry and gas regimes.The present article examines a passive system for emergency cool-down of a nuclear power facility with two loops (Fig. 1): loop for cooling down the reactor facility and an ammonia cooling loop. A characteristic of the system studied here is the lack of blow-offs intended for removing uncondensed gases.The purpose of the cool-down loop is to remove heat directly from the reactor facility. It consists of sections of heat exchange with the reactor loop and condensation of the vapor formed. The water coolant moves from the bottom of the heatexchange section by means of an ascending flow, where it is heated to the temperature of saturation, evaporation, and superheating of the steam. The superheated steam flows along the discharge steam lines into the ammonia heat-exchanger, which releases heat to the cooling loop with ammonia, after which it returns to the entrance of the heat-exchange section.As it moves through the heat-exchange section, the coolant is heated by neutron and gamma radiation, which forms radiolytic gases. In the case of a closed loop without blow-offs, the uncondensed gas -hydrogen and oxygen -accumulates in the coolant, which can disrupt the functioning of the facility, specifically, lower the operating efficiency of the condenser and, as a result, disrupt coolant circulation.General Approach to Modeling the Water-Chemistry and Gas Regime in the Loop of a Passive System. The present article proposes an approach to modeling the water-chemistr...