Experimental (solid+liquid) phase equilibria of (alkan-1-ol+benzonitrile), (amine+benzonitrile) binary mixtures, and (decan-1-ol+decylamine+benzonitrile) ternary mixtures

Solubility of perfumery and fragrance raw materials based on cyclohexane in 1-octanol under ambient and high pressures up to 900 MPa

“…Table 1S includes the direct experimental results of the SLE, temperatures, T 1 /K versus x 1 , the mole fraction of the solute and c 1 , the activity coefficient of 1-octanol in the saturated solution. 15) in the binary system of {1-octanol (1) + CCA (2)}.…”

“…Solid solubilities have been determined using a dynamic (synthetic) method described previously [10][11][12][13][14][15]. The compound was provided under the nitrogen in the dry box.…”

“…Many factors that control the phase behaviour of organic substances with other liquids, especially with alcohols, have been discussed in recently published papers focusing on amines and nitriles [10][11][12][13][14][15]. In every system measured, the (liquid + liquid) phase equilibrium, (LLE), or for the crystalline solutes the SLE was observed as that for simple eutectic binary mixtures with immiscibility in the liquid phase.…”

“…Thermophysical constants of pure substances: melting temperature, T fus ; enthalpy of fusion, D fus H, as determined from differential scanning calorimetry (DSC) data; change of heat capacity at melting temperature, D fus C p ; molar volume at T = 298.15 K, V 298:15 …”

Volumetric properties of binary mixtures of (acetonitrile + amines) at several temperatures with application of the ERAS model

“…This paper reports volumetric properties of {acetonitrile + n-propylamine (PA), or + n-butylamine (BA), or + di-npropylamine (DPA), or + di-n-butylamine (DBA), or + triethylamine (TEA), or + t-butylamine (BA)}, as a function of composition, at temperatures between T = (293. 15 Thermodynamics properties of binary mixtures of nitrile with amines have been studied by Chaudhari [5] (liquid-vapor equilibria and excess molar volume of acetonitrile + diethylamine), Checoni and Francesconi [6] (excess molar enthalpy of acetonitrile + diethylamine, ou + s-butylamine), Nagata and Gotoh [7] {(vapor-liquid) and (liquid-liquid) phase equilibria and excess molar enthalpy of acetonitrile + aniline or n-butylamine), Domańska and Marciniak [8] {(solid-liquid) phase diagrams of acetonitrile + hexylamine, or octylamine, or 1,3-diaminopropane and (liquid-liquid) phase diagrams of octylamine, or decylamine + propanenitrile, or + butanenitrile)}, Domańska and Marciniak [9] (solid-liquid phase diagrams of benzenonitrile + hexylamine, or octylamine, or decylamine, or 1,3-diaminopropane), Grolier et al [10] (heat capacities and densities of acetonitrile + triethylamine), Pathak et al [11] (excess molar enthalpies and excess molar volumes of acetonitrile + 1-aminobutane, or 1-amino-2-methylpropane, or 2-aminobutane, or 2-amino-2-methylpropane), De Schaefer et al [12] (molar excess volumes of 1,4-dioxane + acetonitrile, n-butylamine + acetonitrile and n-butylamine + 1,4-dioxane at different temperatures).…”