Experimental and theoretical insights into thetransinfluence of organo-sulfur and -selenium ligands in 5,6-membered palladium(ii) cationic pincer complexes based on iminophosphoranes

Abstract

Novel iminophosphorane based heterotridentate SNS and SNSe ligands with the general formula MeSC6H4P(Ph2)=NC6H4ER (ER= SMe 3a, SPh 3b, SeMe 3c, SePh 3d) and their corresponding Pd(II) cationic complexes with tetrafluoroborate...