Experimental and modeling studies of density and viscosity behavior of a live fluid due to CO₂injection at reservoir condition

Abstract

In this study, highly accurate measurements of density and dynamic viscosities of a recombined live oil and its mixture with additional CO2 were performed. The experiments were carried out under pressure and temperature gradients found in Brazilian Pre-salt reservoirs, that is, in the pressure range from (27.6 to 68.9) MPa and at (333.15 and 353.15) K. The assumption of volume change on mixing is evaluated from the experimental results, and the influence of pressure and temperature on the volume change upon mixing is assessed. The densities of mixtures are calculated considering (i) the excess volume approach, and (ii) no volume change. The densities are better correlated using the excess volume approach with Average Absolute Deviations (AAD) of 0.03%. Thirteen mixing rules of viscosity are examined by comparing the predicted values with the experimental viscosity of the recombined live oil + CO2 mixture. The performance of some rules using compositional fractions (molar, volume and weight) is also evaluated. Thus, a total of 28 different ways to calculate the mixture viscosities were tested in this study. The worst result was obtained with Bingham’s method, leading to 148.6% AAD. The best result was obtained from Lederer’s method with 2% AAD and a maximum deviation of 5.8% using volume fractions and the fitting parameter α. In addition, deviations presented by the predictive methods of Chevron, Double log, and Kendall did not exceed 9% AAD, using weight fractions (Chevron and Double log) and molar fractions (Kendall and Monroe).

Evaluation of CO2enhanced oil recovery and CO2storage potential in oil reservoirs of petroliferous sedimentary basin, China

“…Crude oil viscosity is an important parameter for screening suitable CO 2 -EOR reservoirs [50]. However, not all the crude oil viscosity of the reservoir is available in the reservoir data.…”

Experimental optimization of Waste Cooking Oil ethanolysis for biodiesel production using Response Surface Methodology (RSM)

“…Many scientific studies have shown that human activity is the main cause of these global problems [1,2]. Indeed, the massive development of transport, the rapid growth of polluting industries, and excessive energy consumption, have largely contributed to the depletion of natural resources and to environmental degradation through the release of greenhouse gases in particular CO 2 , responsible for global warming and climate change [1,[3][4][5]. So, several alternative energy sources derived straightforwardly or in a roundabout from the sun, the wind, hydropower, bioenergy and biofuels or from geothermal energy of the Earth [6] are created and executed to deliver a scope of energy administrations, including power, warming, cooling, and biofuels.…”