“…Dissociation mechanisms, such as defect assisted dissociation, impact ionization by free carriers, thermal dissociation, and Auger decay in neutral and charged impurities, have been invoked to support the idea of exciton-related photocurrent. 22,23 However, if this were indeed the case, then nanostructures, such as nanowires, wherein the mechanism we propose has no effect, should nonetheless show exciton-related peaks. Examining the literature of photocurrent measurements of, e.g., ZnO and GaN nanowires shows mostly step responses, as expected.…”