Exciton and biexciton properties in GaN nanocolumn: dependence on morphology and diameter

Abstract

We have investigated how the morphology and diameter of GaN nanocolumn affect the optical properties of exciton and biexciton. We measured photoluminescence (PL) of excitons in GaN nanocolumns at low temperature and found that the PL spectra depend on the column diameter. Changing the distance between the sample and the collimating lens, it was established that this phenomenon is due to the z ‐polarized PL radiated from the side surface. This result proves that the nano‐scale morphology produces a change in the optical properties. In addition, to elucidate the mechanism causing the increase of the biexciton binding energy observed in a previous experiment, we calculated the exciton binding energies by the variational method and also estimated their sizes. From the calculated results we can expect that the only biexcitons experience spatial confinement effect even when the nanocolumn width is much larger than the exciton Bohr radius. (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

Fabrication of GaN nanowires by a vapor–liquid–solid method using metal–organic chemical vapor deposition

“…The activation energy for FX (12.8 meV) is lower than the reported value (³28 meV), 18) which might be due to the reduced quantum confinement effect by the thicker NWs in the present study. 20)…”