Exchange-Coupling Behavior in SrFe12O19/La0.7Sr0.3MnO3 Nanocomposites

Abstract

Magnetically hard-soft (100-x) SrFe12O19–x wt % La0.7Sr0.3MnO3 nanocomposites were synthesized via a one-pot auto-combustion technique using nitrate salts followed by heat treatment in air at 950 °C. X-ray diffraction (XRD), transmission electron microscopy (TEM), and vibrating sample magnetometry (VSM) were used to characterize the structural and magnetic properties of the samples. XRD spectra revealed the formation of a mixture of ferrite and magnetite phases without any trace of secondary phases in the composite. Microstructural images show the proximity grain growth of both phases. The room temperature hysteresis loops of the samples showed the presence of exchange-coupling between the hard and soft phases of the composite. Although saturation magnetization reduced by 41%, the squareness ratio and coercivity of the nanocomposite improved significantly up to 6.6% and 81.7%, respectively, at x = 40 wt % soft phase content in the nanocomposite. The enhancement in squareness ratio and coercivity could be attributed to the effective exchange-coupling interaction, while the reduction in saturation magnetization could be explained on the basis of atomic intermixing between phases in the system. Overall, these composite particles exhibited magnetically single-phase behavior. The adopted synthesis method is low cost and rapid and results in pure crystalline nanocomposite powder. This simple method is a promising way to tailor and enhance the magnetic properties of oxide-based hard-soft magnetic nanocomposites.

Enhancement of the maximum energy product in Ba0.5Sr0.5Fe12O19/Y3Fe5O12 nanocomposites synthesized by the co-precipitation method

“…With the addition of a high content of YIG (x = 0.2 to 0.4), the values of H c and H n decrease, which is due to dipolar interaction rather than intergrain exchange interaction, which is similar to previous reports [15,16,31,32]. The exchange force interaction on the soft moments are weakened and the dipolar interaction amongst the soft grains becomes significant [33].…”

Dynamics of Superparamagnetic Iron Oxide Nanoparticles with Various Polymeric Coatings

“…It can be easily noticed that peaks at the diffractogram are significantly broadened in comparison with those of microcrystalline magnetite, indicating the nanocrystalline nature of the materials studied. The size of crystallites was determined from the line widths of all identified peaks using Scherrer’s formula, D = kλ/βcosθ , where D is the average crystallite size, λ is the wavelength of X-ray used (1.5406 Å), k is a constant (shape factor ~0.9), θ is the angle of diffraction, and β is the full width at half maximum (FWHM) [49,50].…”

Towards hard-magnetic behavior of CoFe2O4 nanoparticles: a detailed study of crystalline and electronic structures, and magnetic properties

“…As milling with t m = 1–10 min, M r / M s > 0.5 reflects the exchange coupling between neighboring grains/NPs. 52 Beyond these t m values, the magnetostatic interaction between grains plays a dominant role because M r / M s < 0.5. Surprisingly, the as-prepared sample ( t m = 0) also belongs to the magnetostatic interaction ( M r / M s < 0.5).…”