Abstract:In the present work, we report on the synthesis of Sc 2 S 3 , ScCuS 2 and BaScCuS 3 powders using a method based on oxides sulfidation and modification of their properties. The crystal structures and morphology of samples are verified by XRD and SEM techniques. Thermal stability has been studied by DTA which has revealed that Sc 2 S 3 decomposes to ScS through melting at 1877 K. ScCuS 2 and BaScCuS 3 melt incongruently at temperatures of 1618 K and 1535 K, respectively. The electronic structure calculations sh… Show more
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