In this paper, a 3D nitrogen-doped carbon network with excellent adsorption properties was prepared for bisphenol S (BPS) removal from water. An optimized sample B-T700-N3 with high Langmuir specific surface area as well as plentiful heteroatoms was screened out. Benefiting from the synergistic effect of conjugation and hydrogen bonding between the adsorbent and bisphenol S, B-T700-N3 demonstrated superior adsorption performance. The maximum adsorption amount (q max,e ) of the B-T700-N3 at equilibrium was determined to be up to 91 mg/g, which was comparable or even higher than that of the state-of-the-art reported adsorbents. Experimental results illustrated that this adsorbent could also effectively remove other bisphenols (BPA, BPAF) from water. Overall, this novel adsorbent demonstrated a competitive performance for bisphenols removal in aqueous solution and can be a highly interesting candidate for industrial applications.