Motor vehicle emissions have been identified as a major source of particulates, and have been
associated with adverse health effects and decreased ambient air quality. Recent published studies
have shown that Fischer−Tropsch fuels can reduce particulate emissions. The fuel composition,
temperature, and pressure affect the kinetics of a chemical reaction and ultimately the yield of
end products. To see how the above factors impact the particulate yields, D-2 diesel and two
Fischer−Tropsch fuels, Shell MDS and Mossgas COD, were investigated in this study over a
pressure range of 5 to 24 atm and temperature range of 1000 to 2300 °C. All experiments were
conducted in a modified single-pulse reflected shock tube. Fuels were injected using a high-pressure liquid injector. The results from Leco carbon analysis indicated that for most test
conditions, Shell MDS had the lowest particulate yield compared to D-2 diesel followed by Mossgas
COD. At relatively low temperatures (∼1150 °C) and high temperatures (∼2250 °C) the particulate
yields decreased for all fuels tested. At higher pressures an increase in particulate yield was
observed. An attempt was made to correlate the observed difference in soot yields to physical
properties and chemical composition of the investigated fuels. The results are well in agreement
with previous studies that relate lower sulfur and aromatic contents to lower particulate yields
for the test conditions studied. No direct benefit was seen from a high cetane number on particulate
emissions.