“…It is worth noting that the positive value of Δ G ° for HA indicates an endothermic process, while the negative value of Δ G ° for Ti-HA indicates the spontaneous nature of the adsorption process. 5,59 This shows the different behaviors of the Ti-HA surface for Sr( ii ) adsorption because of Ti doping. The increase in the negative Δ G ° value with increasing temperature supports the energetically favorable adsorption at higher temperatures for Sr( ii ) as shown in Table 3.…”
The present study explores the potential of hydroxyapatite (HA) and titanium-doped hydroxyapatite (Ti-HA) for the efficient removal of radioactive strontium (Sr-90) from contaminated water. Both the HA and Ti-HA were...
“…It is worth noting that the positive value of Δ G ° for HA indicates an endothermic process, while the negative value of Δ G ° for Ti-HA indicates the spontaneous nature of the adsorption process. 5,59 This shows the different behaviors of the Ti-HA surface for Sr( ii ) adsorption because of Ti doping. The increase in the negative Δ G ° value with increasing temperature supports the energetically favorable adsorption at higher temperatures for Sr( ii ) as shown in Table 3.…”
The present study explores the potential of hydroxyapatite (HA) and titanium-doped hydroxyapatite (Ti-HA) for the efficient removal of radioactive strontium (Sr-90) from contaminated water. Both the HA and Ti-HA were...
“…The IR band at 2926 cm −1 represents symmetric stretching vibration of -CH 2 , the peak observed at 2245 cm −1 corresponds to CN stretching of nitrile group, C=O stretching is indicated by the peak at 1734 cm −1 . The IR bands at 1038 and 566 cm −1 are assigned to the P-O vibration stretching of HAP, and these two bands indicate the existence of apatite intercalated with a polymeric chain [30], the IR bands at 1563, 1508 cm −1 could be attributed to -NO stretching, and the band at 1169 cm −1 could be due to C-O stretching.…”
A gamma induced copolymerization process was applied to modify hydroxyapatite prepared from eggshell. The composite material was characterized by different physicochemical methods, and then it was used for removal of Sr 2+ and Co 2+ ions from aqueous solutions as a function of pH, temperature, time, interfering ions, and initial Sr 2+ and Co 2+ concentrations by applying batch adsorption technique. The maximum removal was obtained at pH 6, and 8 for Sr 2+ and Co 2+ ions respectively. Sorbents regeneration was successful with HCl eluent. Results showed good fitting to Freundlich isotherm than Langmuir. Kinetic data was well described by pseudo-second order equation.
“…[14][15][16][17][18]. Zeolite, silica and clays have been used under their raw form [19][20][21][22], after chemical modification [23][24][25][26][27], magnetite incorporation [5,28], or extractant impregnation [29]. Sorbents impregnated with Prussian Blue and analogues have also been successfully tested for Sr(II) removal [30,31].…”
Bi-functionalization of silica particles increases Sr(II) sorption properties.• Methacrylic (80%)/amidoxime (20%) substitution ratio is optimum.• Maximum sorption capacity reaches 1.57 mmol Sr g −1 at pH 8.• Total Sr(II) desorption and weak loss in sorption properties at the fifth recycling.
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