Gas stations are important emissions source of benzene (C 6 H 6 ), toluene (C 7 H 8 ), ethylbenzene (C 8 H 10 ), and ortho, meta and para-xylene (C 8 H 10 )-better known by the acronym BTEX. The objective of this study was to determine the concentrations of BTEX compounds in the ambient air of ten gas stations in the cities of Salvador and Feira de Santana, Bahia, Brazil and evaluate the health risks to workers. Passive samplers diffusive of the Radiello®, containing activated carbon as adsorbent, were used. The samplers were exposed for 8 h and then the analytes were recovered by chemical desorption with CS 2 and determined by GC-FID. The BTEX concentrations found in the ambient air of gas stations ranged from 46.72 -435.43 μg·m −3 for benzene;25.54 -342.46 μg·m −3 for toluene, 7.10 -30.07 μg·m −3 for ethylbenzene, 9.36 -89.73 μg·m −3 for m, p-xylene and 9.79 -52.29 μg·m −3 for o-xylene. The concentrations of toluene, ethylbenzene and xylenes found in gas stations were lower than the limits recommended by the US NIOSH and NR-15 of the Ministry of Labour of Brazil; however, it should be considered the risks due to chronic exposure of workers. Benzene concentrations in three gas stations were above the exposure limit recommended by NIOSH (3.20 × 10 2 μg·m −3). Samplings were also held outdoors at 250 m of two gas stations. The total concentrations of the BTEX compounds were equal to 24.97 and 35.51 μg·m −3