We
report a computational fluid dynamics–discrete element
method (CFD-DEM) simulation study on the interplay between mass transfer
and a heterogeneous catalyzed chemical reaction in cocurrent gas-particle
flows as encountered in risers. Slip velocity, axial gas dispersion,
gas bypassing, and particle mixing phenomena have been evaluated under
riser flow conditions to study the complex system behavior in detail.
The most important factors are found to be directly related to particle
cluster formation. Low air-to-solids flux ratios lead to more heterogeneous
systems, where the cluster formation is more pronounced and mass transfer
more influenced. Falling clusters can be partially circumvented by
the gas phase, which therefore does not fully interact with the cluster
particles, leading to poor gas–solid contact efficiencies.
Cluster gas–solid contact efficiencies are quantified at several
gas superficial velocities, reaction rates, and dilution factors in
order to gain more insight regarding the influence of clustering phenomena
on the performance of riser reactors.