Erratum

Martín, Gonzalo; Ascanio, Julián; Rodriguez, Jesús Rodríguez

doi:10.1002/kin.550260513

Cited by 3 publications

(4 citation statements)

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“…According to [21][22][23] the one-loop renormalization group equations (RGEs) for the SM gauge couplings are given by…”

Section: Perturbative Unificationmentioning

confidence: 99%

Effective Higgs theories in supersymmetric grand unification

Zheng¹

2017

Eur. Phys. J. C

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The effective Higgs theories at the TeV scale in supersymmetric SU(5) grand unification models are systematically derived. Restricted to extensions on 5 H containing the Higgs sector we show that only two types of real (vectorlike) models and one type of chiral model are found to be consistent with perturbative grand unification. While the chiral model has been excluded by the LHC data, the fate of perturbative unification will be uniquely determined by the two classes of vector-like models.

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“…According to [21][22][23] the one-loop renormalization group equations (RGEs) for the SM gauge couplings are given by…”

Section: Perturbative Unificationmentioning

confidence: 99%

Effective Higgs theories in supersymmetric grand unification

Zheng¹

2017

Eur. Phys. J. C

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“…The gas-phase thermolysis of diethyl cyanomethyl amine was reported [1] to generate nearly equal amounts of ethylene and HCN, plus N-ethylmethanaldimine, by way of a clean, nonchain radical reaction mechanism. The initial step proposed for the reaction was the splitting of an ethyl radical from the parent molecule, with a C 9 N bond dissociation energy (BDE) estimated as close to the mea-…”

Section: Introductionmentioning

confidence: 99%

Gas-phase thermolysis ofN-cyanomethyl-N-ethyl aniline,N-cyanomethyl-N-ethyl-p-anisidine, andN-cyanomethyl-N-ethyl-p-nitroaniline

Martín¹,

Ascanio²,

Rodríguez³

1998

Int. J. Chem. Kinet.

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N-cyanomethyl-N-ethyl aniline (CEAN) and N-cyanomethyl-N-ethyl-p-anisidine (CEPA) have been thermolyzed in a stirred-flow reactor, in the range of 510-560 ЊC, pressures of 7-11 torr and residence times of using toluene as carrier gas. N-cyanomethyl-N-0.5-0.9 s, ethyl-p-nitroaniline (ECNA) was thermolyzed at 640ЊC and 13% conversion. Ethylene and HCN formed in 43% yield each as products from all three starting materials. Phenyl methanaldimine and p-anisidyl methanaldimine were also products of CEAN and CEPA, respectively. The consumption of CEAN and CEPA showed first-order kinetics for a three-fold increase of reactant inflow and initial conversions of up to 40 percent. The following Arrhenius equations were obtained from the rate coefficients for the production of ethylene: CEAN: k ϭ CEPA:The re-15.10Ϯ0.74 15.61Ϯ0.29 10 exp(Ϫ238 Ϯ 11 kJ/mol·RT); k ϭ 10 exp(Ϫ246 Ϯ 4 kJ/mol·RT). sults are explained by means of radical, nonchain thermolysis mechanisms. The thermochemistry of relevant reaction steps has been estimated from thermochemical parameters calculated by using the semiempirical AM1 method.

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“…For the thermal generation of silenes from allylsilanes [3,13,14], a concerted retroene elimination of propene was proposed. Thermal decomposition of allylamines [9][10][11][12] has shown that the rate of pyrolysis is dependent on the substituent on the N atom and on the acidity of the H atom likely to be transferred, suggesting a polar transition state with a, perhaps, less concerted mechanism than for the allyl ethers.…”

Section: Introductionmentioning

confidence: 99%

“…generation of some carbon-heteroatom double bonds; among these can be cited C‫ס‬O [4][5][6], C‫ס‬S [7,8], C‫ס‬N [9][10][11][12], C‫ס‬Si [13,14], and recently, C‫ס‬P [15,16].…”

Section: Introductionmentioning

confidence: 99%