In this paper, we study several properties of the second power I 2 ∆ of a Stanley-Reisner ideal I ∆ of any dimension. As the main result, we prove that S/I ∆ is Gorenstein whenever S/I 2 ∆ is Cohen-Macaulay over any field K. Moreover, we give a criterion for the second symbolic power of I ∆ to satisfy (S 2 ) and to coincide with the ordinary power, respectively. Finally, we provide new examples of Stanley-Reisner ideals whose second powers are Cohen-Macaulay.