2013
DOI: 10.1016/j.talanta.2013.01.024
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Enzymatic electrochemical detection coupled to multivariate calibration for the determination of phenolic compounds in environmental samples

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Cited by 17 publications
(7 citation statements)
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“…Oxidation products can be reduced electrochemically in the electrode surface and therefore an electrochemical signal directly proportional to the concentration of the phenolic compound is obtained when H 2 O 2 is present in excess. 40 Based on these results, it was possible to determine phenolic compounds using electroanalytical method developed. As the disposable biosensor allow good sensitivity and high-speed scanning, it was employed to determine phenolic compounds in wastewater from coffee washing (environmental sample), using the voltammetry square wave technique.…”
Section: Square Wave Voltammetry (Swv)mentioning
confidence: 99%
“…Oxidation products can be reduced electrochemically in the electrode surface and therefore an electrochemical signal directly proportional to the concentration of the phenolic compound is obtained when H 2 O 2 is present in excess. 40 Based on these results, it was possible to determine phenolic compounds using electroanalytical method developed. As the disposable biosensor allow good sensitivity and high-speed scanning, it was employed to determine phenolic compounds in wastewater from coffee washing (environmental sample), using the voltammetry square wave technique.…”
Section: Square Wave Voltammetry (Swv)mentioning
confidence: 99%
“…Hernandez et al. 48 reported the horseradish peroxidase enzymatic electrochemical detection of phenolic compounds such as phenol, p ‐aminophenol, p ‐chlorophenol, hydroquinone and pyroca‐techol at a detection limit of 60×10 −7 M. Kafi and Chen 49 developed a amperometric biosensor using horseradish‐peroxidase (HRP) and methylene blue (MB) with chitosan on Au‐modified TiO 2 nanotube arrays for the detection of p ‐nitrophenol and it was found that the detection limit of 9×10 −8 M in the linear range from 3×10 −7 to 1.2×10 −4 M. The comparison of the electrochemical detection of phenolic compounds of catechol, p ‐cresol and p ‐nitrophenol obtained in the presented study with the previous results reported in the literature is summarized in Table 1, showing that the proposed electrochemical sensor exhibited an excellent sensitivity with simultaneous sensing measurements towards catechol, p ‐cresol and p ‐nitrophenol. Moreover, the electrochemical method developed in this study for the simultaneous sensing of catechol, p ‐cresol and p ‐nitrophenol phenolic compounds possesses the advantages of a satisfied detection limit with high sensitivity, in conjunction with the electrode preparation method being very simple.…”
Section: Resultsmentioning
confidence: 99%
“…8B. 151 Hernandez et al 152 demonstrated the electrochemical detection of phenolic compounds in environmental samples based on the horseradish peroxidase enzymatic reaction, by means of SWV. Fig.…”
Section: Detection Of Phenolic Compoundsmentioning
confidence: 99%