“…Instead, recycling allows for valuable metals such as cobalt and nickel to be recovered, lowering the raw material demand and securing an alternative raw materials supply chain, gaining independence from exporting economies ( Figure 1 ) ( Helbig et al., 2018 ; Mineral Commodity Summaries 2020, 2020 ; Olivetti et al., 2017 ; Skeete et al., 2020 ; Sommerville et al., 2021 ; Steward et al., 2019 ). Moreover, efficient recycling processes can help to avoid energy- and emission-intensive material processing ( Ciez and Whitacre, 2019 ; Dunn et al., 2012 ; Gaines et al., 2011 ; Hao et al., 2017 ; Mohr et al, 2020 ; Xiong et al., 2020 ). Current recycling processes can be mainly classified under three types, namely pyrometallurgical, hydrometallurgical, and direct recycling ( Chen et al., 2019 ; Dunn et al., 2012 ; Elwert et al., 2018 ; Fan et al., 2020 ; Gaines, 2018 ; Harper et al., 2019 ; Huang et al., 2018 ).…”
Section: Introductionmentioning
confidence: 99%
“…It is thus crucial to identify cost-cutting/profit-increasing opportunities in the recycling process through detailed techno-economic assessments, in order to incentivize the industry to increase its recycling capacity. Indeed, to date, several techno-economic studies of LIB recycling have been published, analyzing the recycling cost of several battery chemistries and various recycling methods ( Fan et al., 2020 ; Li et al., 2018 ; Samarukha, 2020 ; Xiong et al., 2020 ; Yang et al., 2018 ). However, most techno-economic studies are limited by either the system boundaries of their assessment (e.g.…”
Summary
Economically viable electric vehicle lithium-ion battery recycling is increasingly needed; however routes to profitability are still unclear. We present a comprehensive, holistic techno-economic model as a framework to directly compare recycling locations and processes, providing a key tool for recycling cost optimization in an international battery recycling economy. We show that recycling can be economically viable, with cost/profit ranging from (−21.43 - +21.91) $·kWh
−1
but strongly depends on transport distances, wages, pack design and recycling method. Comparing commercial battery packs, the Tesla Model S emerges as the most profitable, having low disassembly costs and high revenues for its cobalt. In-country recycling is suggested, to lower emissions and transportation costs and secure the materials supply chain. Our model thus enables identification of strategies for recycling profitability.
“…Instead, recycling allows for valuable metals such as cobalt and nickel to be recovered, lowering the raw material demand and securing an alternative raw materials supply chain, gaining independence from exporting economies ( Figure 1 ) ( Helbig et al., 2018 ; Mineral Commodity Summaries 2020, 2020 ; Olivetti et al., 2017 ; Skeete et al., 2020 ; Sommerville et al., 2021 ; Steward et al., 2019 ). Moreover, efficient recycling processes can help to avoid energy- and emission-intensive material processing ( Ciez and Whitacre, 2019 ; Dunn et al., 2012 ; Gaines et al., 2011 ; Hao et al., 2017 ; Mohr et al, 2020 ; Xiong et al., 2020 ). Current recycling processes can be mainly classified under three types, namely pyrometallurgical, hydrometallurgical, and direct recycling ( Chen et al., 2019 ; Dunn et al., 2012 ; Elwert et al., 2018 ; Fan et al., 2020 ; Gaines, 2018 ; Harper et al., 2019 ; Huang et al., 2018 ).…”
Section: Introductionmentioning
confidence: 99%
“…It is thus crucial to identify cost-cutting/profit-increasing opportunities in the recycling process through detailed techno-economic assessments, in order to incentivize the industry to increase its recycling capacity. Indeed, to date, several techno-economic studies of LIB recycling have been published, analyzing the recycling cost of several battery chemistries and various recycling methods ( Fan et al., 2020 ; Li et al., 2018 ; Samarukha, 2020 ; Xiong et al., 2020 ; Yang et al., 2018 ). However, most techno-economic studies are limited by either the system boundaries of their assessment (e.g.…”
Summary
Economically viable electric vehicle lithium-ion battery recycling is increasingly needed; however routes to profitability are still unclear. We present a comprehensive, holistic techno-economic model as a framework to directly compare recycling locations and processes, providing a key tool for recycling cost optimization in an international battery recycling economy. We show that recycling can be economically viable, with cost/profit ranging from (−21.43 - +21.91) $·kWh
−1
but strongly depends on transport distances, wages, pack design and recycling method. Comparing commercial battery packs, the Tesla Model S emerges as the most profitable, having low disassembly costs and high revenues for its cobalt. In-country recycling is suggested, to lower emissions and transportation costs and secure the materials supply chain. Our model thus enables identification of strategies for recycling profitability.
“…To meet out the demand for high energy and power density of electrochemical energy storage devices, the material development plays a dramatic role [13,14]. Comprehensively, various EES devices are available; however, batteries [15][16][17][18] and supercapacitors [19][20][21] are considered as two main classes of EES devices due to their high energy and power densities [12,[22][23][24][25][26]. In the view of safety and life cycle, supercapacitors headed over the batteries [27,28], but they are backward in the energy density [29].…”
HIGHLIGHTS• This article reviewed the recent progress on material challenges, charge storage mechanism, and electrochemical performance evaluation of supercapatteries.• Supercapatteries bridge the gap between supercapacitors (low energy density) and batteries (low power density). Fig. 1 a Ragone plot of various electrochemical energy conversion and storage devices [43]. b Schematic illustration of charge storage mechanism of EDL capacitor in porous carbon electrode. c Representation of EDLC structures: Helmholtz model, Gouy-Chapman model and Gouy-Chapman-Stern model. Schematic representation of the charge storage mechanisms in pseudocapacitor; d Intercalation (bulk redox) and e surface redox Nano-Micro Lett.(2020) 12:85Page 5 of 46 85 Table 1 Classification of various energy storage devices according to their charge storage mechanisms NFCS non-Faradaic capacitive storage = EDLC storage, CFS capacitive Faradaic storage = pseudocapacitive storage, NCFS non-capacitive Faradaic storage = battery-type storage Device Supercapattery Battery Supercapacitor Hybrid supercapacitor EDLC Pseudocapacitors
“…[ 7,10,11 ] K seems to be of particular interest as it has properties similar to those of lithium. [ 12–15 ] While it has a reduction potential lower than that of lithium in alkylcarbonate, [ 16 ] calculated by Marcus, graphite has been shown to insert this element with good capacity retention and a gravimetric capacity of 250 mA h g −1 , unlike the insertion of Na, [ 16–18 ] which is a less polarizable cation than K + and larger than Li + . Na + combines the two disadvantages (the wrong size and the wrong electronic density).…”
Manganese oxide LiMn2O4 (LMO) is one of the most promising cathode materials because it benefits from the low cost and availability of manganese, a high electrochemical stability, and a neutral environmental impact. In the same vein, the full or partial replacement of lithium salt in electrolyte by a more available and less expensive potassium salt contributes to reducing the environmental impact of batteries. Herein, the impact of the partial or total replacement of LiPF6 by KPF6 in a binary mixture of alkyl carbonate (EC/EMC) for LMO/graphite full battery is reported. The physicochemical properties of the electrolyte and its consequence on the kinetic and thermodynamic intercalation controls of each cation on cyclability are explored. Without protection with an additive, at a high current density (1 C), the nonselective intercalation of the two cations induces an optimum observed with an equimolar salt composition (0.5 m LiPF6 + 0.5 m KPF6), whereas in the presence of 5% of fluoroethylene (FEC), the replacement of part of the lithium is achievable without significant loss of performance. However, LMO/Gr cycling seems to depend on the discharge current density.
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