2021
DOI: 10.1007/s11004-021-09981-7
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Ensemble Smoother with Multiple Data Assimilation as a Tool for Curve Fitting and Parameter Uncertainty Characterization: Example Applications to Fit Nonlinear Sorption Isotherms

Abstract: The ensemble smoother with multiple data assimilation (ES-MDA) coupled to a normal-score transformation is used to fit a Langmuir isotherm curve to estimate its parameters (Sm and b) and their uncertainty. The highlights of this work are three: i) the ES-MDA can be used as a curve fitting procedure, ii) the ES-MDA provides also a full uncertainty quantification about the fitted parameters and iii) for the specific case of the Langmuir isotherm, parameter Sm is well identified with little uncertainty, while par… Show more

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Cited by 4 publications
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“…However, there are many cases in practice in which the empirical data do not adequately fit these types of functions but correspond to two different behaviours dependent on the variation of the independent variable. This study presents a new type of single variable function, named the function of double asymptote, which allows the acceptance of new empirical laws, unlike other more complex processes such as the one shown in Godoy et al [1], and those showing a single asymptote are usually studied using the empirical Hurst's law [2]. A function of double asymptote of a single variable is one that presents an infinite approximation to a straight line (horizontal, vertical, or oblique), i.e., an asymptotic behaviour, at two different values, and these functions have been called y 2A (x).…”
Section: Introductionmentioning
confidence: 99%
“…However, there are many cases in practice in which the empirical data do not adequately fit these types of functions but correspond to two different behaviours dependent on the variation of the independent variable. This study presents a new type of single variable function, named the function of double asymptote, which allows the acceptance of new empirical laws, unlike other more complex processes such as the one shown in Godoy et al [1], and those showing a single asymptote are usually studied using the empirical Hurst's law [2]. A function of double asymptote of a single variable is one that presents an infinite approximation to a straight line (horizontal, vertical, or oblique), i.e., an asymptotic behaviour, at two different values, and these functions have been called y 2A (x).…”
Section: Introductionmentioning
confidence: 99%