2012
DOI: 10.1007/s00340-012-4986-9
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Enhancement of up-conversion luminescence in Zn2SiO4:Yb3+, Er3+ by co-doping with Li+ or Bi3+

Abstract: Yb 3+ /Er 3+ co-doped Zn 2 SiO 4 ceramics are rapidly synthesized by the microwave radiation method. Green and red up-conversion emissions are observed in Zn 2 SiO 4 : Yb 3+ , Er 3+ ceramics under 980 nm excitation. The influence of co-doped Li + or Bi 3+ ion on luminescence intensity for the phosphors has been investigated. At Li + or Bi 3+ doping concentration of 1 mol%, up-converted green emission can be increased by 6 times and 20 times, respectively. It is believed that co-doped Li + or Bi 3+ ion results … Show more

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Cited by 44 publications
(29 citation statements)
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(37 reference statements)
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“…289,290 Hao and co-workers reported another intriguing manner to tailor the local symmetry of Ln 3+ in ferroelectric BaTiO 3 :Yb,Er, where Er 3+ ions are noncentrosymmetric in the lattice ( Figure 17b). 291 When applying an external electric field along the direction of spontaneous polarization, the lattice elongated and promoted the asymmetry of the BaTiO 3 host, leading to lower symmetry around Er 3+ ions.…”
Section: Efficiency Enhancement Of Upconversion Emissionsmentioning
confidence: 96%
“…289,290 Hao and co-workers reported another intriguing manner to tailor the local symmetry of Ln 3+ in ferroelectric BaTiO 3 :Yb,Er, where Er 3+ ions are noncentrosymmetric in the lattice ( Figure 17b). 291 When applying an external electric field along the direction of spontaneous polarization, the lattice elongated and promoted the asymmetry of the BaTiO 3 host, leading to lower symmetry around Er 3+ ions.…”
Section: Efficiency Enhancement Of Upconversion Emissionsmentioning
confidence: 96%
“…Similar strategy is also frequently reported for UC nanoparticles. For example, a small amount of Bi 3+ (1–4 mol%) in β‐NaYF 4 :Yb 3+ ,Ln 3+ (Ln 3+ = Er 3+ , Tm 3+ and Ho 3+ ) nanocrystals results in significantly enhanced (≈10–36‐fold) UC emission intensity …”
Section: Tailoring Up‐conversion Intensitymentioning
confidence: 99%
“…However, compared with conventional luminescence materials, weak luminescence intensity of UC nano/micro-crystals is still the main limitation for their practical applications. In recent years, various methods have been developed to improve the luminescence intensity, such as surface plasmon of metal nanoparticles, crystal surface coating and core/shell synthesis [8][9][10][11]. However, it is still a challenge for researchers to obtain nano/micro-crystals with high UC luminescence intensity.…”
Section: Introductionmentioning
confidence: 99%