Enhancement of surface properties on Low Density Polyethylene packaging films using various fluorination routes

Peyroux, Jérémy; Dubois, Marc; Tomasella, Éric; Frézet, Lawrence; Kharitonov, A. P.

doi:10.1016/j.eurpolymj.2014.12.040

Cited by 16 publications

(2 citation statements)

References 46 publications

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“…3.3 FTIR spectra of MA onto HDPE Generally, the FTIR spectra have been extensively used to identify functional groups of polymers. [42][43][44] In this study, FTIR data of neat HDPE and HDPE-g-MA were showed in Fig. 4.…”

Section: Influence Of Reaction Temperature Of Ma Onto Hdpementioning

confidence: 68%

Synthesis and Non-Isothermal Crystallization Behaviors of Maleic Anhydride onto High Density Polyethylene

Ahn¹,

Jeon²,

Baek³

et al. 2016

J. Korean Ceram. Soc

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The grafting reaction for maleic anhydride (MA) onto high density polyethylene (HDPE) was investigated from solution process with initiators. The chemical modification of neat HDPE was carried out with various contents of MA (3-21 wt.%) and initiator (0.2-1 wt.%) at different temperature (80-130 o C). The grafting degree was obtained from the titration and the highest grafting degree was 3.1%. The grafting degree increased as the content of MA and initiator increased, however, the highest grafting degree was demonstrated for a particular content of MA and initiator. In the non-isothermal crystallization kinetics, the Ozawa model was unsuitable method to investigate the crystallization behavior of MA onto HDPE, whereas the Avrami and Liu models found effective. The crystallization rate was accelerated as the cooling rate increased, but postponed by combination of MA onto neat HDPE backbone.

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Section: Influence Of Reaction Temperature Of Ma Onto Hdpementioning

confidence: 68%

Synthesis and Non-Isothermal Crystallization Behaviors of Maleic Anhydride onto High Density Polyethylene

Ahn¹,

Jeon²,

Baek³

et al. 2016

J. Korean Ceram. Soc

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show abstract

“…For a wide range of polymers, the reaction with elemental fluorine leads to the appearance of oxygen-containing functional groups such as C-OH, >C=O, -C(O)F, -COOH even in hydrocarbon-based materials [ 65 , 83 ]. Introduction of oxygen into a chemical structure of polymers can be evidently related to its presence as a contaminant in initial reagents, reaction chamber or to interaction of the fluorinated material with atmospheric oxygen after fluorination [ 84 ]. Such interaction might be possible due to the formation of long-lived electron lone pairs in the chemical structure of the fluorinated polymer layer that was detected by electron spin resonance (ESR) measurements [ 85 , 86 , 87 ].…”

Section: Chemical Composition and Laminate Structure Of Fluorinated Membranesmentioning

confidence: 99%

Effect of Direct Fluorination on the Transport Properties and Swelling of Polymeric Materials: A Review

et al. 2021

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Fluorine-containing polymers occupy a peculiar niche among conventional polymers due to the unique combination of physicochemical properties. Direct surface fluorination of the polymeric materials is one of the approaches for the introduction of fluorine into the chemical structure that allows one to implement advantages of fluorinated polymers in a thin layer. Current review considers the influence of the surface interaction of the polymeric materials and membranes with elemental fluorine on gas, vapor and liquid transport as well as swelling and related phenomena. The increase in direct fluorination duration and concentration of fluorine in the fluorination mixture is shown to result mostly in a reduction of all penetrants permeability to a different extent, whereas selectivity of the selected gas pairs (He-H2, H2-CH4, He-CH4, CO2-CH4, O2-N2, etc.) increases. Separation parameters for the treated polymeric films approach Robeson’s upper bounds or overcome them. The most promising results were obtained for highly permeable polymer, polytrimethylsilylpropyne (PTMSP). The surface fluorination of rubbers in printing equipment leads to an improved chemical resistance of the materials towards organic solvents, moisturizing solutions and reduce diffusion of plasticizers, photosensitizers and other components of the polymeric blends. The direct fluorination technique can be also considered one of the approaches of fabrication of fuel cell membranes from non-fluorinated polymeric precursors that improves their methanol permeability, proton conductivity and oxidative stability.

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Nanostructured Polymer Composites with Modified Carbon Nanotubes

Kharitonov

Ткачев

Burakova

et al. 2017

Handbook of Composites From Renewable Materials

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Enhancement of surface properties on Low Density Polyethylene packaging films using various fluorination routes

Cited by 16 publications

References 46 publications

Synthesis and Non-Isothermal Crystallization Behaviors of Maleic Anhydride onto High Density Polyethylene

Synthesis and Non-Isothermal Crystallization Behaviors of Maleic Anhydride onto High Density Polyethylene

Effect of Direct Fluorination on the Transport Properties and Swelling of Polymeric Materials: A Review

Nanostructured Polymer Composites with Modified Carbon Nanotubes

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