Functionalized
interfaces enhancing phase-change processes have immense applicability
in thermal management. Here, a methodology for fabrication of surfaces
enabling extreme boiling heat transfer performance is demonstrated,
combining direct nanosecond laser texturing and chemical vapor deposition
of a hydrophobic fluorinated silane. Multiple strategies of laser
texturing are explored on aluminum with subsequent nanoscale hydrophobization.
Both superhydrophilic and superhydrophobic surfaces with laser-engineered
microcavities exhibit significant enhancement of the pool boiling
heat transfer. Surfaces with superhydrophobic microcavities allow
for enhancements of a heat transfer coefficient of over 500%. Larger
microcavities with a mean diameter of 4.2 μm, achieved using
equidistant laser scanning separation, induce an early transition
into the favorable nucleate boiling regime, while smaller microcavities
with a mean diameter of 2.8 μm, achieved using variable separation,
provide superior performance at high heat fluxes. The enhanced boiling
performance confirms that the Wenzel wetting regime is possible during
boiling on apparently superhydrophobic surfaces. A notable critical
heat flux enhancement is demonstrated on superhydrophobic surfaces
with an engineered microstructure showing definitively the importance
and concomitant effect of both the surface wettability and topography
for enhanced boiling. The fast, low-cost, and repeatable fabrication
process has great potential for advanced thermal management applications.