Enhanced Tb(III) luminescence by d10 transition metal coordination

Tri- and Mono-Nuclear Zinc(II) Complexes Based on Half- and Mono-Salamo Chelating Ligands

“…The 2D supramolecular structure of complex 2 is composed of two parts. The first part was linked by intermolecular N2-H2B···O9, N4-H4B···O16 and C29-H29···O15 [41,64] hydrogen bonding interactions. The other part was made up of the C-Cl···π [27], C-H···π stacking interactions.…”

“…The Zn(II) ion does not produce spectroscopic or magnetic signals because of its 3d 10 4s 0 electronic configuration, when the Zn(II) ion forms complexes with ligands, the complexes generally have fluorescence properties [40,41]. Although these salamo-type Zn(II) complexes are currently being studied and developed, the solvent effects on the salamo-type Zn(II) complexes are still very rare.…”

Structural and Hirshfeld Surface Analyses of a Novel Hetero-Tetranuclear CuII-NaI Bis(Salamo)-Based Coordination Compound

“…Salen-type ligands and their coordination compounds have been extensively investigated [1][2][3][4][5][6][7][8][9][10] for their catalytic activities [11][12][13][14][15], biological activities [16][17][18][19][20][21][22], supramolecular architectures [23][24][25][26][27][28][29][30][31][32], and fluorescence properties [33][34][35][36][37][38]. To improve the properties of Salen-type ligands, in recent years, Nabeshima and our group's researches mostly concentrated on the syntheses of Salamo-type ligands, which are a class of novel Salen-type analogues [39][40][41][42][43][44][45][46][47][48]…”

Structural and Luminescent Properties of Heterobimetallic Zinc(II)-Europium(III) Dimer Constructed from N2O2-Type Bisoxime and Terephthalic Acid

“…Salen-and salamo-type complexes have been extensively investigated in organometallic chemistry and modern coordination chemistry for several decades [7][8][9][10][11], their complexes are well-known for their potential applications in many areas, such as catalysts [12,13], biological fields [14][15][16][17][18][19][20][21], supramolecular buildings [22][23][24][25][26], molecular recognitions [27][28][29][30][31], magnetic [32][33][34][35][36][37] and luminescence [38][39][40][41][42][43][44][45] materials and so forth. Self-assembling processes of a metallohost complex with auxiliary organic ligands are usually utilized in the building of metal-organic framework (MOF) materials [46,47].…”

“…The O 4 site of 3-alkoxy-induced Salen-type ligand is suitable for lanthanide(III) atoms to prepare 3d-4f heteronuclear complexes. These 3d-4f heterobimetallic Salen-type complexes have been diffusely studied [14,34,37,44] in which acetate (OAc -) combine plays a key role in assembling 3d and 4f metals [52], however, 3d-4f heterobimetallic Salamo-type complexes have been rarely reported, especially the auxiliary ligands were introduced [53].…”