2007
DOI: 10.1016/j.chemosphere.2007.02.010
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Enhanced photoelectrocatalytic performance of Zn-doped WO3 photocatalysts for nitrite ions degradation under visible light

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Cited by 145 publications
(55 citation statements)
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“…Thus, WO 3 behaves as photoanode and doped metal oxides served as photocathode [87]. Interestingly, doping of Zn 2+ failed to trap the CB electrons due to its filled electronic configuration and therefore suppressed the hydrogen evolution [87], while improved the decomposition of nitrite under applied bias, with NaCl electrolyte [88]. The chloride similar to hydroxide ion can be oxidized by the VB hole directly to produce chlorine radical, which also M a n u s c r i p t 14 reacts with nitrite in the degradation process.…”
Section: Doping With Metal/nonmetal Ionsmentioning
confidence: 98%
“…Thus, WO 3 behaves as photoanode and doped metal oxides served as photocathode [87]. Interestingly, doping of Zn 2+ failed to trap the CB electrons due to its filled electronic configuration and therefore suppressed the hydrogen evolution [87], while improved the decomposition of nitrite under applied bias, with NaCl electrolyte [88]. The chloride similar to hydroxide ion can be oxidized by the VB hole directly to produce chlorine radical, which also M a n u s c r i p t 14 reacts with nitrite in the degradation process.…”
Section: Doping With Metal/nonmetal Ionsmentioning
confidence: 98%
“…The incident photon to current efficiency (IPCE) was measured using a 250 W xenon lamp (SVX 1450, Müller Germany) equipped with a monochromator (Acton Spectra Pro-150, U.S.A.) that was used as light source. 23,24 The photon density of monochromatic light was monitored by an irradiatometer (S370, UDT Instruments, and U.S.A.).…”
Section: Methodsmentioning
confidence: 99%
“…Semiconductors like Bi 12 TiO 20 [2], Nb 2 O 5 [3], Sm 2 Ti 2 S 2 O 5 [4], Bi 2 O 3 [5], ZnWO 4 [6], Bi 2 WO 6 [7], NaTaO 3 [8], CaIn 2 O 4 [9], WO 3 [10], TiO 2 [11], Fe 2 O 3 [12], ZnO [13], etc, finds extensive application either in water splitting/degradation of organic compounds. Among the various semiconductors, TiO 2 is extensively used photocatalyst due to its chemical and biological inertness, water insolubility, non-toxicity, resistance against photo-chemical corrosion and its cheap availability.…”
Section: Introductionmentioning
confidence: 99%