The plasma polymerization is one of the methods of resist film coating. It is known that polymer depositon rate has maximum value in the glow zone of discharge (GZD). But the activation of monomer molecules in GZD may lead to their considerable destruction. To keep the initial molecular structure of at least one of monomers the following experiment on copolymerization of two monomers was carried out. Inside the flowing tube reactor the vapour of one monomer, for example, xylene, was filled in the glow zone of argon plasma, and the vapour of another monomer, (methyl methacrylate) was filled outside this zone, in the lower part of the gas flow. The silicon substrate was placed perpendicularly to the reactor axis under GZD. The thickness of polymer film was controled by means of laser interferometer.The experiment revealed that the film deposition rate is significantly greater for copolymerization of two monomers than for polymerization of each of monomers separatly when another one is not filled. Thus the principal possibility of copolymerization of monomers in the after glow zone of discharge (AGZD) has been demonstrated, moreover only one monomer is activated in the plasma during this process, while the structure of another one is preserved.