“…0.59 T in this case. Coercivity values higher than this critical value have already be obtained by decreasing the particle diameter using organometallic route [22,42] or polyol route [19] or by improving the NR shape as well [43].…”
Section: Discussionmentioning
confidence: 99%
“…The coercivity of cobalt NRs is strongly dependent on their size, shape and crystalline structure [19,20]. Several groups worldwide have recently measured relatively high coercivity on single-crystalline hcp cobalt rods and wires prepared following polyol process and organometallic approaches [21,22].…”
Rare-earth free permanent magnets were produced by consolidation of cobalt nanorods synthesized by the polyol process exhibiting a mean diameter in the range 10 to 30 nm. Compactions of magnetically prealigned rod assemblies at various pressures and temperatures were carried out to make dense materials. Bulk magnets exhibiting a very good mechanical strength and an energy product as high as 65 kJ.m-3 were obtained. The best results were obtained when the compaction conditions were soft enough to preserve the morphology and alignment of the rods in the final material, as revealed by X-ray diffraction and neutron scattering. For the first time the bottom-up approach is convincingly reported to produce bulk magnets without the addition of any matrix, the obtained nanostructured materials exhibit coercivity much higher than the AlNiCo magnets and can fill the performance "gap" between hexaferrites and rare-earth based magnets.
“…0.59 T in this case. Coercivity values higher than this critical value have already be obtained by decreasing the particle diameter using organometallic route [22,42] or polyol route [19] or by improving the NR shape as well [43].…”
Section: Discussionmentioning
confidence: 99%
“…The coercivity of cobalt NRs is strongly dependent on their size, shape and crystalline structure [19,20]. Several groups worldwide have recently measured relatively high coercivity on single-crystalline hcp cobalt rods and wires prepared following polyol process and organometallic approaches [21,22].…”
Rare-earth free permanent magnets were produced by consolidation of cobalt nanorods synthesized by the polyol process exhibiting a mean diameter in the range 10 to 30 nm. Compactions of magnetically prealigned rod assemblies at various pressures and temperatures were carried out to make dense materials. Bulk magnets exhibiting a very good mechanical strength and an energy product as high as 65 kJ.m-3 were obtained. The best results were obtained when the compaction conditions were soft enough to preserve the morphology and alignment of the rods in the final material, as revealed by X-ray diffraction and neutron scattering. For the first time the bottom-up approach is convincingly reported to produce bulk magnets without the addition of any matrix, the obtained nanostructured materials exhibit coercivity much higher than the AlNiCo magnets and can fill the performance "gap" between hexaferrites and rare-earth based magnets.
“…Such design has been used successfully for broadband ferromagnetic measurements. 8,20,21 Microwave generation and detection An Anritsu MG3695C signal generator is used to produce a continuous-wave microwave signal with a frequency between 8 MHz and 50 GHz. The microwave signal transmitted through the CPW is rectified by a Herotek DZR50024 zero-bias Schottky diode.…”
We built a broadband Electron Paramagnetic Resonance (EPR) spectrometer capable of field- and frequency sweep experiments under field-, microwave amplitude- and microwave frequency-modulation detection modes (HM, AM, and FM, respectively)....
“…Along this direction, coercive fields of 0.35 T and 0.63 T at 300K and 4K respectively are measured for packing fraction of 0.38. Ferromagnetic resonance and magnetic torque measurements have evidenced values of magnetocrystalline anisotropy constants K1 and K2 of more than 40% higher than the ones of Co hcp bulk, possibly due to the surface anisotropy [41].…”
Section: Magnetic Properties Of 2d Arrays Of Perpendicular Nanorodsmentioning
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