Insulation materials play an extremely important role in the thermal protection of aerospace vehicles. Here, aluminum carbon aerogels (AlCAs) are designed for the thermal protection of aerospace. Taking AlCA with a carbonization temperature of 800 °C (AlCA–800) as an example, scanning electron microscopy (SEM) images show an integrated three-dimensional porous frame structure in AlCA–800. In addition, the thermogravimetric test (TGA) reveals that the weight loss of AlCA–800 is only ca. 10%, confirming its desirable thermal stability. Moreover, the thermal conductivity of AlCA–800 ranges from 0.018 W m−1 K−1 to 0.041 W m−1 K−1, revealing an enormous potential for heat insulation applications. In addition, ANSYS numerical simulations are carried out on a composite structure to forecast the thermal protection ability of AlCA–800 acting as a thermal protection layer. The results uncover that the thermal protective performance of the AlCA–800 layer is outstanding, causing a 1185 K temperature drop of the structure surface that is exposed to a heat environment for ten minutes. Briefly, this work unveils a rational fabrication of the aluminum carbon composite aerogel and paves a new way for the efficient thermal protection materials of aerospace via the simple and economical design of the aluminum carbon aerogels under the guidance of ANSYS numerical simulation.