2019
DOI: 10.3390/e21080813
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Enhanced Electron Scattering upon Ion Relocation in BaVS3 at 69 K

Abstract: The present study deals with the anomalous heat capacity peak and thermal conductivity of BaVS 3 near the metal-insulator transition present at 69 K. The transition is related to a structural transition from an orthorhombic to monoclinic phase. Heat capacity measurements at this temperature exhibit a significant and relatively broad peak, which is also sample dependent. The present study calculates the entropy increase during the structural transition and we show that the additional entropy is caused b… Show more

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