Abstract-Electron paramagnetic resonance (EPR) signals of Bi2+ ions have been detected in the EPR spec trum of manganese , bismuth , and tin doped PbWO 4 single crystals irradiated by xenon and mercury lamps at 100 K. The parameters of the Zeeman, hyperfine, and superhyperfine interactions and the localization of Bi 2+ ions have been determined.