Enhanced carbon dioxide capture upon incorporation of N,N′-dimethylethylenediamine in the metal–organic framework CuBTTri

McDonald, Thomas M.; D’Alessandro, Deanna M.; Krishna, Rajamani; Long, Jeffrey R.

doi:10.1039/c1sc00354b

Cited by 486 publications

(318 citation statements)

References 39 publications

Supporting

Mentioning

304

Contrasting

Unclassified

Order By: Relevance

“…Such gating behaviour has been found recently in a two-fold interpenetrated framework and also in a partially interpenetrated framework. 5,20 In the present case, structural transformations occur under pressure for CO 2 showing multiple steps at 195 K. It is noteworthy that this is the first time such an adsorption profile has been reported for IRMOF-9. We attribute this to careful handling and activation procedures (See ESI †).…”

Section: -19mentioning

confidence: 72%

Does functionalisation enhance CO₂ uptake in interpenetrated MOFs? An examination of the IRMOF-9 series

et al. 2014

View full text Add to dashboard Cite

show abstract

Section: -19mentioning

confidence: 72%

Does functionalisation enhance CO₂ uptake in interpenetrated MOFs? An examination of the IRMOF-9 series

et al. 2014

View full text Add to dashboard Cite

show abstract

“…23,51,[58][59][60][61][62][63][64] Functionalization of these types of MOFs may be carried out by post-synthetic modification (PSM) on the open metal sites, 47,[65][66][67][68][69] by post-synthetic metal exchange, 70 or direct use of functionalized ligands. 23,51,[58][59][60] The amines (or sulfonates) PSM of porous organic polymers (POPs, COFs, etc.…”

Section: Discussionmentioning

confidence: 99%

Low concentration CO2 capture using physical adsorbents: Are metal–organic frameworks becoming the new benchmark materials?

Belmabkhout¹,

Guillerm²,

Eddaoudi³

2016

Chemical Engineering Journal

275

167

View full text Add to dashboard Cite

KeywordsCO 2 capture, traces CO 2 removal, air capture, physical adsorbents, MOFs AbstractThe capture and separation of traces and concentrated CO 2 from important commodities such as CH 4 , H 2 , O 2 and N 2, is becoming important in many areas related to energy security and environmental sustainability. While trace CO 2 concentration removal applications have been modestly studied for decades, the spike in interest in the capture of concentrated CO 2 was motivated by the need for new energy vectors to replace highly concentrated carbon fuels and the necessity to reduce emissions from fossil fuel-fired power plants. CO 2 capture from various gas streams, at different concentrations, using physical adsorbents, such as activated carbon, zeolites, and metal-organic frameworks (MOFs), is attractive. However, the adsorbents must be designed with consideration of many parameters including CO 2 affinity, kinetics, energetics, stability, capture mechanism, in addition to cost. Here, we perform a systematic analysis regarding the key technical parameters that are required for the best CO 2 capture performance using physical adsorbents. We also experimentally demonstrate a suitable 2 material model of Metal Organic Framework as advanced adsorbents with unprecedented properties for CO 2 capture in a wide range of CO 2 concentration. These recently developed class of MOF adsorbents represent a breakthrough finding in the removal of traces CO 2 using physical adsorption.This platform shows colossal tuning potential for more efficient separation agents.

show abstract

“…The functionalities of the components can be varied and the flexibility in size and geometry has progressed toward more than 21,000 various MOFs being studied and announced, with their specific surface areas ranging widely from 1000 to 10,000 m 2 /g [50,51]. They have popularized many previous studies because of their excellent adsorption capacities, their specificity for the adsorption of CO 2 [52][53][54], H 2 [55][56][57], or hazardous gases, and their great selectivities [58][59][60][61].…”

Section: Metal-organic Framework and Porous Polymersmentioning

confidence: 99%

A review: methane capture by nanoporous carbon materials for automobiles

Choi¹,

Jeong²,

Choi³

et al. 2016

Carbon letters

View full text Add to dashboard Cite

Global warming is considered one of the great challenges of the twenty-first century. In order to reduce the ever-increasing amount of methane (CH 4 ) released into the atmosphere, and thus its impact on global climate change, CH 4 storage technologies are attracting significant research interest. CH 4 storage processes are attracting technological interest, and methane is being applied as an alternative fuel for vehicles. CH 4 storage involves many technologies, among which, adsorption processes such as processes using porous adsorbents are regarded as an important green and economic technology. It is very important to develop highly efficient adsorbents to realize techno-economic systems for CH 4 adsorption and storage. In this review, we summarize the nanomaterials being used for CH 4 adsorption, which are divided into non-carbonaceous (e.g., zeolites, metal-organic frameworks, and porous polymers) and carbonaceous materials (e.g., activated carbons, ordered porous carbons, and activated carbon fibers), with a focus on recent research.

show abstract

Enhanced carbon dioxide capture upon incorporation of N,N′-dimethylethylenediamine in the metal–organic framework CuBTTri

Cited by 486 publications

References 39 publications

Does functionalisation enhance CO₂ uptake in interpenetrated MOFs? An examination of the IRMOF-9 series

Does functionalisation enhance CO₂ uptake in interpenetrated MOFs? An examination of the IRMOF-9 series

Low concentration CO2 capture using physical adsorbents: Are metal–organic frameworks becoming the new benchmark materials?

A review: methane capture by nanoporous carbon materials for automobiles

Contact Info

Product

Resources

About

Enhanced carbon dioxide capture upon incorporation of N,N′-dimethylethylenediamine in the metal–organic framework CuBTTri

Cited by 486 publications

References 39 publications

Does functionalisation enhance CO2 uptake in interpenetrated MOFs? An examination of the IRMOF-9 series

Does functionalisation enhance CO2 uptake in interpenetrated MOFs? An examination of the IRMOF-9 series

Low concentration CO2 capture using physical adsorbents: Are metal–organic frameworks becoming the new benchmark materials?

A review: methane capture by nanoporous carbon materials for automobiles

Contact Info

Product

Resources

About

Does functionalisation enhance CO₂ uptake in interpenetrated MOFs? An examination of the IRMOF-9 series

Does functionalisation enhance CO₂ uptake in interpenetrated MOFs? An examination of the IRMOF-9 series