A method for calculating CO 2 emissions from coal combustion at the TPP is developed on the basis of carbon emission factors, taking into account the heat value of coal and heat losses due to the presence of unburnt carbon in ash. The values of СО 2 emissions at Ukrainian TPPs are obtained. Specific emissions of carbon dioxide are closely 1100 g СО 2 /kWh, which correlates with high specific consumption of fuel for electricity production at the TPP. Кеуwordsenvironment, thermal power plant, flue gases, carbon dioxide, emission factor, calorific value.