This study presents experimental results on the production,
characterization,
and applications of three-dimensionally designed piezoelectric–triboelectric
hybrid nanogenerators. The hybrid nanofiber mats were manufactured
using poly(vinylidene fluoride) and thermoplastic polyurethane as
the piezoelectric and triboelectric counter materials, respectively,
by the simultaneous electrospinning process. Surface-engineering agents
such as poly(vinylpyrrolidone), reduced graphene oxide nanoplates
(rGO NPs), and zinc oxide nanowires (ZnO NWs) were utilized in three-dimensional
decoration stages. The nanofiber surfaces were roughened using the
sacrifice method, followed by the application of electrospraying and
hydrothermal growth techniques to decorate the nanofibers with rGO
NPs and ZnO NWs, thereby enhancing the device. The resulting hybrid
nanogenerators were subjected to periodic compression via an applied
force, resulting in a 75.0% increase in voltage density and a 169.23%
increase in current density compared to the neat hybrid nanogenerator,
thanks to the surface roughening treatment. Furthermore, the decorations
of rGO NPs and ZnO NWs on the nanofibers contributed to a 271.80%
increase in voltage density and a 230.77% increase in current density,
reaching values of 2.35 kV/m2 and 3.40 mA/m2, respectively. The nanogenerators were also tested in various applications,
including energy storage, device powering, and textile sensors, to
demonstrate their practicality.