Energy from CO2 using capacitive electrodes – Theoretical outline and calculation of open circuit voltage

Paz‐Garcia, Juan Manuel; Schaetzle, Olivier; Biesheuvel, P.M.; Hamelers, H.V.M.

doi:10.1016/j.jcis.2013.11.081

Cited by 34 publications

(35 citation statements)

References 31 publications

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“…Activated carbon electrodes assembled with an ion-exchange membrane[27,28,29,30,31,32,33] A perm-selective membrane separates from the solution in the cell. It is either a cation exchange membrane or an anion exchange membrane, respectively permeable to positive or negative ions.…”

mentioning

confidence: 99%

Electrode kinetics in the “capacitive mixing” and “battery mixing” techniques for energy production from salinity differences

Marino

Misuri

Ruffο

et al. 2015

Electrochimica Acta

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mentioning

confidence: 99%

Electrode kinetics in the “capacitive mixing” and “battery mixing” techniques for energy production from salinity differences

Marino

Misuri

Ruffο

et al. 2015

Electrochimica Acta

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“…The ion exchange membranes (IEMs) are key in EDR and their behavior is based on the concept of permselectivity which was first studied by Donnan . The electric potential at the membrane/solution surface, known as the Donnan potential, causes the exclusion of co‐ions from the membrane matrix and can be used as a measure of the permselectivity …”

Section: Electrochemical Technologiesmentioning

confidence: 99%

Electrodialytic processes in solid matrices. New insights into battery recycling. A review

Villén-Guzmán

Arhoun

Vereda‐Alonso

et al. 2019

J of Chemical Tech & Biotech

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Electrodialytic remediation has been widely applied to the recovery of different contaminants from numerous solid matrices, solving emerging issues of environmental concern. Results and conclusions reported in studies about real contaminated matrices are summarized in this work. The influence of pH value on the treatment effectiveness has been widely proved, highlighting the phenomenon of ‘water splitting’ in the membrane surface. This dissociation of water molecules is related to the ‘limiting current’ which it is desirable to exceed at the anion exchange membrane in order to produce the entering of protons toward the solid matrix. Other important parameters for the optimization of the technique, such as the current density and the liquid/solid ratio, are also discussed through the revision of studies using real solid matrices. This work also focuses on the pioneer proposal of electrokinetic technologies for the recycling of lithium ion batteries, considering the relevance of waste properties in the design and optimization of the technique. From a thorough literature revision, it could be concluded that further experimental results are needed to allow an optimal application of the technique to the rising problem of residues from batteries. The main aim of this work is to take the first steps in the recovery of valuable metals such as Li and Co from spent batteries, incorporating principles of green chemistry. © 2019 Society of Chemical Industry

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“…The equilibrium reactions describing the chemical system in the diffuse layer and the bulk solution are [13,14]:…”

Section: The Physicochemical Modelmentioning

confidence: 99%

Modeling of Electric Double-Layers Including Chemical Reaction Effects

Paz‐Garcia

Johannesson

Ottosen

et al. 2014

Electrochimica Acta

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Energy from CO2 using capacitive electrodes – Theoretical outline and calculation of open circuit voltage

Cited by 34 publications

References 31 publications

Electrode kinetics in the “capacitive mixing” and “battery mixing” techniques for energy production from salinity differences

Electrode kinetics in the “capacitive mixing” and “battery mixing” techniques for energy production from salinity differences

Electrodialytic processes in solid matrices. New insights into battery recycling. A review

Modeling of Electric Double-Layers Including Chemical Reaction Effects

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