Encapsulation of Sandwich POM in MIL-101 as Efficient Oxidative Desulfurization Catalyst of DBT

Liang, Jiaen; Fan, Mengwei; Wu, Wenjie; Wu, Mengmeng; Cai, Wangshui; Gao, Xinxing; Huang, Ting‐Ting; Han, Rui

doi:10.1007/s10562-022-04057-5

Catal Lett

2022

DOI: 10.1007/s10562-022-04057-5

|View full text |Cite

Encapsulation of Sandwich POM in MIL-101 as Efficient Oxidative Desulfurization Catalyst of DBT

Jiaen Liang

Mengwei Fan

Wenjie Wu

et al.

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2023

2024

Publication Types

Select...

Article4

Relationship

Self Cite1

Independent3

Authors

Journals

Cited by 4 publications

References 45 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Cationic Exchange of Evans‐Showell Polyoxometalate to Construct Efficient Hydrodesulfurization Catalyst

Liang

Wang

et al. 2023

ChemistrySelect

Self Cite

View full text Add to dashboard Cite

In this paper, a simple cationic exchange method was proposed to increase the Co/Mo ratio in the Evans-Showell polyoxometalate to the desired 0.5 with both Mo and Co atoms in one molecule. This approach was proved successfully by X-ray diffraction, X-ray fluorescence spectrometer, infrared spectroscopy, and thermogravimetric analyzer. Then, the obtained Evans-Showell-type polyoxometalate was used as a superior precursor to construct efficient hydrodesulfurization catalyst, and the dibenzothiophene evaluation results showed that the hydrodesulfurization reaction turnover frequency, the rate constant, and the dibenzothiophene conversion are 1.8 × 10 À 3 s À 1 , 6.4 × 10 À 7 mol g À 1 s À 1 , and 95.2 %, respectively, illustrating the excellent hydrodesulfurization performance of the catalyst. The cationic exchange approach promises the Mo and Co atoms in one molecule and the desired proximity of them, leading to a higher dispersion of MoS 2 nanoparticles, a higher percent of CoMoS active phase and the excellent hydrodesulfurization performance for dibenzothiophene consequently.

show abstract

Cationic Exchange of Evans‐Showell Polyoxometalate to Construct Efficient Hydrodesulfurization Catalyst

Liang

Wang

et al. 2023

ChemistrySelect

Self Cite

View full text Add to dashboard Cite

show abstract

A critical review on recent trends in metal-organic framework-based composites as sustainable catalysts for environmental applications

Haruna,

Zango,

Tanimu

et al. 2024

Journal of Environmental Chemical Engineering

View full text Add to dashboard Cite

Investigating the catalytic performance of polyoxometalate immobilized on magnetic chitosan in the oxidative desulfurization process

Gooneh-Farahani,

Anbia

2024

Journal of Industrial and Engineering Chemistry

View full text Add to dashboard Cite

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

hi@scite.ai

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Encapsulation of Sandwich POM in MIL-101 as Efficient Oxidative Desulfurization Catalyst of DBT

Cited by 4 publications

References 45 publications

Cationic Exchange of Evans‐Showell Polyoxometalate to Construct Efficient Hydrodesulfurization Catalyst

Cationic Exchange of Evans‐Showell Polyoxometalate to Construct Efficient Hydrodesulfurization Catalyst

A critical review on recent trends in metal-organic framework-based composites as sustainable catalysts for environmental applications

Investigating the catalytic performance of polyoxometalate immobilized on magnetic chitosan in the oxidative desulfurization process

Contact Info

Product

Resources

About