2023
DOI: 10.1002/anie.202307507
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Enabling New Approaches: Recent Advances in Processing Aliphatic Polycarbonate‐Based Materials

Peiran Wei,
Gulzar A. Bhat,
Donald J. Darensbourg

Abstract: Aliphatic polycarbonates (aPCs) have become increasingly popular as functional materials due to their biocompatibility and capacity for on‐demand degradation. Advances in polymerization techniques and the introduction of new functional monomers have expanded the library of aPCs available, offering a diverse range of chemical compositions and structures. To accommodate the emerging requirements of new applications in biomedical and energy‐related fields, various manufacturing techniques have been adopted for pr… Show more

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Cited by 17 publications
(8 citation statements)
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“…The cross-linked structure of polycarbonate confers high strength and toughness and makes it promising for hard tissue repair. 106 Chemically cross-linked cured polycarbonate-based DBE typically consist of polycarbonate diols, diesters, and photoinitiators. Hydrolysis of ester bonds is the main degradation modality of polycarbonate elastomers, and polycarbonate elastomers used as tissue repair are also affected by biodegradation enzymes represented by lipases.…”
Section: Synthesis and Properties Of Dbe For Tissue Repairmentioning
confidence: 99%
“…The cross-linked structure of polycarbonate confers high strength and toughness and makes it promising for hard tissue repair. 106 Chemically cross-linked cured polycarbonate-based DBE typically consist of polycarbonate diols, diesters, and photoinitiators. Hydrolysis of ester bonds is the main degradation modality of polycarbonate elastomers, and polycarbonate elastomers used as tissue repair are also affected by biodegradation enzymes represented by lipases.…”
Section: Synthesis and Properties Of Dbe For Tissue Repairmentioning
confidence: 99%
“…This CO 2 incorporation has raised interest in its potential for commercialization as an exemplar of carbon capture and utilization technology. PO/CO 2 copolymerization remains a vibrant and highly researched topic, necessitating the development of novel and efficient catalytic systems. …”
Section: Introductionmentioning
confidence: 99%
“…8,9 Recyclable aliphatic polycarbonate products have demands in wide applications like environmental protection, adhesives, electronic devices, biomedical materials and automobile accessories. 10,11 In the reported studies, cocatalysts of DMC to enrich the function of products and optimize the reaction conditions are seldom explored.…”
Section: Introductionmentioning
confidence: 99%