Elemental carbon and hydrogen concentrations as the main factors in gas-phase graphene synthesis: Quantitative fourier-transform infrared spectroscopy study

Musikhin, Stanislav; Fortugno, Paolo; Endres, Torsten; Dreier, Thomas; Daun, Kyle J.; Schulz, Christof

doi:10.1016/j.carbon.2022.11.024

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The Functionalization Of Graphene-based Composites1

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2023

2024

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Cited by 5 publications

(1 citation statement)

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“…Musikhin et al investigated the gas-phase graphene synthesis under low carbon and high hydrogen concentrations, whereas soot-like graphene was formed at high carbon and low hydrogen concentrations. 30 Dong et al reported on the highly dispersed graphene aerogels using the non-dispersion strategy, which can be directly used for 3D printing. 31…”

Section: The Functionalization Of Graphene-based Compositesmentioning

confidence: 99%

Recent advances in the environmental application of graphene-based composites

Hou,

Zhu,

Yue

et al. 2024

Environ. Sci.: Nano

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Section: The Functionalization Of Graphene-based Compositesmentioning

confidence: 99%

Recent advances in the environmental application of graphene-based composites

Hou,

Zhu,

Yue

et al. 2024

Environ. Sci.: Nano

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Novel Aerosol‐Based Approach toward Mesoporous Silica Nanoparticles

Fortugno,

López-Cámara,

Kruse

et al. 2023

Adv Eng Mater

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This study introduces a novel gas‐phase method for the synthesis of mesoporous silica nanoparticles (MSNs). The method is a two‐step templating approach by first forming silicon‐coated carbon structures in a hybrid microwave‐plasma/hot‐wall reactor followed by an annealing step to produce mesoporous silica with distinct nanostructure and porosity. Two different (sacrificial) carbonaceous templates have been prepared (plasma reactor) and coated (hot‐wall reactor), 2D few‐layer graphene (FLG) flakes and soot‐like fractal aggregates. Results show that the wall thickness of the porous silica structures can be adjusted by changing the concentration of the silicon precursor (monosilane). High monosilane concentrations, however, result in solid silica particles after annealing. Using soot‐like particle templates permitted to control of the shell thickness of the hollow porous particles, while the FLG template results in ultrathin silica sheets after heat treatment. The pore volume and specific surface area increase up to 263 m2 g−1 and 0.6 cm3 g−1, respectively, by the formation of hollow porous particles. An adsorption study on carbamazepine reveals up to ≈86% removal. The gas‐phase aerosol‐based template method presented here offers scalability and versatility, and it is capable of producing MSNs with a controlled structure and porosity by modifying the carbonaceous templates.

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