Electron impact mass spectra of some hexa‐aryloxy‐ and ‐arylamino‐cyclotriphosphazenes

Synthesis and X-ray structural studies of new spiro-cyclotriphosphazenes

“…The elimination of H ؒ could be compared to that observed for hexaphenoxycyclotriphosphazene 6 in which an intramolecular cyclization is associated with nitrogen protonation.…”

Unusual loss of neutral molecules on mass spectrometric decomposition of protonated and cationized phenoxy‐ and phenylaminocyclophosphazenes

“…10 -12 Mass spectrometric decompositions of phenoxy-and phenylaminocyclophosphazenes have been investigated with electron ionisation mass spectrometry. 13,14 Here we report unusual mass spectrometric fragmentation pathways of protonated and cationized phenoxy-and phenylaminocyclophosphazenes 1-4 (their complexes with alkali metal cations) ( Figure 1).…”