2018
DOI: 10.1016/j.eurpolymj.2018.07.050
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Electrochromic strategy for tungsten oxide/polypyrrole hybrid nanofiber materials

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Cited by 30 publications
(15 citation statements)
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“…Compared to typical advanced electrochromic conjugated polymers, , the PFPT film exhibits superior overall performances, especially in the NIR region, including excellent optical contrast, high coloration efficiency, fast response time, good memory effect, as well as outstanding stability against both long-term CV and pulse switching cycling (Table b). The advantageous electrochromic performance, making it a promising visible-to-NIR material for various electrochromic devices, is probably attributable to the introduction of a fluorophenyl substituent on the polythiophene backbone, which benefits the formation of a high-quality PFPT film with a better conjugated structure and a more compact chain arrangement.…”
Section: Resultsmentioning
confidence: 99%
“…Compared to typical advanced electrochromic conjugated polymers, , the PFPT film exhibits superior overall performances, especially in the NIR region, including excellent optical contrast, high coloration efficiency, fast response time, good memory effect, as well as outstanding stability against both long-term CV and pulse switching cycling (Table b). The advantageous electrochromic performance, making it a promising visible-to-NIR material for various electrochromic devices, is probably attributable to the introduction of a fluorophenyl substituent on the polythiophene backbone, which benefits the formation of a high-quality PFPT film with a better conjugated structure and a more compact chain arrangement.…”
Section: Resultsmentioning
confidence: 99%
“…Polypyrrole nanofibers (Ppy NFs), due to their unique conducting properties and one-dimensional (1D) nanostructure, are speculated to attain high-efficiency electron transport properties and the capability of structuration, making them promising candidates for the fabrication of advanced nanoelectronics and nanocomposites. Recently, Ppy NFs have been synthesized and integrated with other nanomaterials, e.g., metals, metal oxides, and nanocarbons, to act as a functional component alone or together with other materials in supercapacitors, electrochromics, electrocatalysts, tissue scaffolds, and soft electronics. Current synthesis techniques for Ppy NFs include the oxidative template method, electrospinning, and interfacial polymerization. Core–shell Ppy NFs can be produced by coating Ppy on the electrospun polymer nanofibers, e.g., polyacrylonitrile, and melt-extruded poly (vinyl alcohol-co-ethylene) nanofibers. , However, the insulating polymer core may confine the electron transfer process only in the conductive Ppy coating layer; huge contact resistance may arise on the interface between the Ppy coating and the polymer core. Irregular Ppy particles, rather than nanofibers, would form on the polymer surface during the coating process.…”
Section: Introductionmentioning
confidence: 99%
“…Its application in EC layers is atypical; until now, the technique has been mostly applied in the biomedical field . Additionally, applications of electrospinning in the energy storage and conversion areas have already been promoted. , In the past, fibrous or 1D morphologies have been shown to be of use for electrochemical redox reactions, where charge transfer occurs much faster compared to thin film technology. , Furthermore, layering composite fibrous layers can also be beneficial to enhance light transmission and light modulation. , …”
Section: Introductionmentioning
confidence: 99%
“…24,25 In the past, fibrous or 1D morphologies have been shown to be of use for electrochemical redox reactions, where charge transfer occurs much faster compared to thin film technology. 26,27 Furthermore, layering composite fibrous layers can also be beneficial to enhance light transmission and light modulation. 28,29 Here, the advantages of electrospinning in EC switchable glass with the formulation of metal NP-loaded TiO 2 composite nanofibers are showcased.…”
Section: Introductionmentioning
confidence: 99%