“…[ 7,76–78 ] However, PDMS contains ether/organosilicon bonds which may be hepatotoxic/nephrotoxic, [ 79–81 ] it may degrade, [ 82,83 ] and its surface chemistry may need to be tuned to minimize biofouling; [ 84–86 ] pyrrole (acknowledged in supplier's safety data sheets (SDSs), which are of variable quality, to display a degree of toxicity, with significant variation in LD50 between species and mode of administration), the photoinitiator (irgacure D‐2959; SDSs indicating it to be somewhat toxic), and PPY (non‐hazardous in supplier's SDSs), which were predicted to be non‐sensitizers of skin, and non‐mutagenic. [ 73,87 ] Here we screen the other components utilized in the printing of PPY‐based structures within PDMS (employing ink formulations composed of mixtures of the monomer pyrrole, PY; the photoinitiator (irgacure D‐2959), dopant (camphorsulfonic acid, CSA; SDSs indicating it to be corrosive and toxic), and a combination of polyethylene glycol (PEG, 10 kDa; SDSs indicating it to be non‐hazardous) and polyethylene glycol dimethyacrylate (PEGDMA, 2 kDa; SDSs variable, often indicated to be an eye irritant, skin sensitizer, and toxic), depicted in Figure ). In silico toxicity screening studies of the ink components (CSA, and PEG, Table S1, Supporting Information) using Derek Nexus (Derek Nexus: 6.0.1, Nexus: 2.2.2) predicted them to be non‐sensitizers of skin, and in silico mutagenicity screening studies using Sarah Nexus (Sarah Nexus: 3.0.0, Sarah Model: 2.0) predicted them to be non‐mutagenic; by contrast, PEGDMA is predicted to plausibly cause chromosome damage, cause irritation of eyes/skin, be a sensitizer of skin (albeit non‐mutagenic).…”