Abstract:Several experimental techniques (conductivity, zeta potential, transmission electronic microscopy, and steady-state fluorescence spectroscopy) have been used to study the formation of mixed colloidal aggregates consisting of a cationic double-chain surfactant, di-dodecyldimethylammonium bromide (di-C12DMAB), and a single-chain alkyltrimethylammonium bromide with 10 and/or 14 carbon atoms (decyltrimethylammonium bromide, C10TAB, and/or tetradecyltrimethylammonium bromide, C14TAB). Special interest has been devo… Show more
“…[10] if R 1. Reported experimental values of j j are close to 6 kT for micelles [12] and highly charged colloids [13] in aqueous media, but also smaller values have been observed depending upon (bare) charge density and ionic strength [8,14,15]. Inserting Eq.…”
We show that the equilibrium size of single-layer shells composed of polyoxometalate macroions is inversely proportional to the dielectric constant of the medium in which they are dispersed. This behavior is consistent with a stabilization mechanism based on Coulomb repulsion combined with charge regulation. We estimate the cohesive energy per bond between macroions on the shells to be approximately ÿ6kT. This number is extracted from analysis based on a charge regulation model in combination with a model for defects on a sphere. The value of the cohesive bond energy is in agreement with the model-independent critical aggregate concentration. This observation points to a new class of thermodynamically stable shell-like objects. We point out the possible relevance our findings have for certain surfactant systems.
“…[10] if R 1. Reported experimental values of j j are close to 6 kT for micelles [12] and highly charged colloids [13] in aqueous media, but also smaller values have been observed depending upon (bare) charge density and ionic strength [8,14,15]. Inserting Eq.…”
We show that the equilibrium size of single-layer shells composed of polyoxometalate macroions is inversely proportional to the dielectric constant of the medium in which they are dispersed. This behavior is consistent with a stabilization mechanism based on Coulomb repulsion combined with charge regulation. We estimate the cohesive energy per bond between macroions on the shells to be approximately ÿ6kT. This number is extracted from analysis based on a charge regulation model in combination with a model for defects on a sphere. The value of the cohesive bond energy is in agreement with the model-independent critical aggregate concentration. This observation points to a new class of thermodynamically stable shell-like objects. We point out the possible relevance our findings have for certain surfactant systems.
“…The aggregation number (N agg ) of Tween-20 micelles in the presence of different wt% of [C 5 mim][BF 4 ] was obtained by fluorescence quenching of pyrene using a cosurfactant cetylpyridinium chloride (CPC) as quencher according to the following equation [36][37][38]. 4 ].…”
Section: Aggregation Number From Fluorescence Quenching Methodsmentioning
“…2-(p-Toluidino)naphthalene-6-sulfonate (TNS, Scheme S2 of supporting materials) is a fluorescence probe, which apart from wavelength shift, contrary to PyCHO, demonstrates a dramatic increase in fluorescence quantum yield upon encountering hydrophobic environment (∼200-fold increase in φ F in 1-octanol versus water) [92,93]. Fig.…”
Section: Fluorescence Probe Behavior Within Aqueous Tx-100 In the Absmentioning
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