2004
DOI: 10.1007/bf03027323
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Electrochemical and interfacial properties of (PEO)10LiCF3SO3−Al2O3 nanocomposite polymer electrolytes using ball milling

Abstract: Electrochemical and interfacial properties of (PEO)10LiCF3SO3-Al2O3 composite polymer electrolytes (CPEs) prepared by either ball milling or stirring are reported. Ball milling was introduced into a slurry preparative technique utilizing PEO, lithium salt and Al2O3 powder ranging from 5 to 15 wt.%. The ionic conductivity was increased by ball milling over a range of temperatures. In particular, a significant increase at low temperature below the melting point of crystalline PEO was observed. Interfacial stabil… Show more

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Cited by 8 publications
(2 citation statements)
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References 14 publications
(21 reference statements)
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“…The dendritic form of Li does not increase in the Li-S cell of a simple arrangement when the PSs can be transferred between the anode and the cathode. The change of liquid electrolyte by polymer one or gel one increases the cyclability performance of Li-S cell through slowing the PS shuttle effect [57][58][59][60][61][62][63][64][65][66]. Polymer electrolyte plays the role of both electrolyte and separator.…”
Section: Cell Configurationmentioning
confidence: 99%
“…The dendritic form of Li does not increase in the Li-S cell of a simple arrangement when the PSs can be transferred between the anode and the cathode. The change of liquid electrolyte by polymer one or gel one increases the cyclability performance of Li-S cell through slowing the PS shuttle effect [57][58][59][60][61][62][63][64][65][66]. Polymer electrolyte plays the role of both electrolyte and separator.…”
Section: Cell Configurationmentioning
confidence: 99%
“…The idea of dispersing inert ceramic fillers into the matrix of polymersalt complexes was proposed originally by Weston and Steele [9] as an attractive approach with an aim to improve mechanical properties of the polymeric films. Subsequently, this approach resulted in additional improvement in thermal, electrical and electrochemical properties of the solid polymer electrolytes [10][11][12][13][14][15][16].…”
Section: Introductionmentioning
confidence: 99%