Thermophysical properties of metals in the melting range are crucial to optimize processes e.g., powder production by atomizing or casting by means of simulation programs. The demand and the availability of these properties is summarized in. [1] Beside viscosity and surface tension the knowledge of the thermal conductivity is of particular importance, however, its direct measurement is extremely difficult because of the long measuring times to reach thermal equilibrium and, therefore, possible chemical reactions between crucible and specimen. Also contact resistance between crucible and sample and convection in the molten state may cause measurement errors. Indirect determination is possible by measurement of the thermal diffusivity and calculation of the thermal conductivity if specific heat capacity and density of the material are known. Results on Al-base alloys have been published by R. E. Taylor and coworkers. [2,3] At thermal diffusivity also problems with the crucible arise by additional heat flow through the crucible and crucible/melt interaction. Such measurement uncertainties are negligible if the electric resistivity is measured. Results on Al-base alloys have been reported. [4,5] For the calculation of the thermal conductivity using the Wiedemann±Franz law the value of the Lorenz number is needed. Experimental results of measurements on metal melts [6,7] have shown that the Lorenz number can be assumed to be close to the theoretical value of Sommerfeld because in the liquid state of metals the heat transport is dominated by free electrons. For this reason, a measurement apparatus has been developed to measure the electric resistivity.The four probe technique was applied to measure the electric resistivity, whereby a cylindrical sample of diameter D = 5 mm is loaded by a direct current I. The electric resistivity r is determined by measuring the voltage drop DU between two probes positioned at a distance of L = 50 mm to 80 mm using the following equation:All these values can be measured with a relatively high accuracy. Systematic errors at the determination of the voltage drop DU because of thermoelectric voltage between the sample and the electrodes can be eliminated by providing a commutator at the power supply in order to change the direction of the electric current and using the mean of the two values in both directions. Measurements in the molten state of a metal are much more difficult than measurements only on solids because the sample must be kept inside of a ceramic tube. This involves that geometric data and sample temperature are more difficult to be determined and the complicate mechanics of the electrodes may lead to increased measurement errors. Therefore, two apparatus have been constructed: one for measurements on solids only at moderate temperatures where ideal conditions can be realized for precise measurements and the second to measure in the solid and in the molten state. By comparing the results in the overlapping temperature range the values of the measurements in the ceramic tube...