Electrical contact effects of flexible self-supporting DNA thin films for storage devices

Abstract

The development of flexible DNA thin films embedded with diverse functional nanomaterials might be beneficial for electronic devices and biosensors. In this work, we fabricated two different methods of electrodes (i.e., metal paste spotted electrodes and metal layer electrodes) on flexible drug- and dye-embedded DNA thin films to examine the electrical and capacitance properties for conduction and energy storage, respectively. Enhanced current and reduced capacitance of drug-embedded DNA thin films compared to pristine DNA with Ag paste electrodes were observed due to the intrinsic characteristics of the drugs. We introduced the e-beam deposition process for fabricating relatively large area metal (such as Au and Al) coated electrodes, which ensures the creation of metal layers on both sides of the flexible thin films while improving metal contact. There was a significant current increase in DNA thin films with metal layer electrodes compared to DNA thin films with Ag paste electrodes. Furthermore, capacitances measured from Au/Dg/Au and Al/Dg/Al capacitors were relatively more stable than Ag paste DNA thin films. The physical properties of our samples might easily be controlled by manipulating functional nanomaterials in DNA thin films and various types of metal layer electrodes. Our self-supporting DNA thin films with integrated nanomaterials and durable metal layer electrodes might be employed in flexible electronic devices such as nanogenerators, skin electronics, and biosensors in the future.

Modulation of Excimer Formation and Photoexcitation Behaviour through DNA‐Surfactant‐Dye Supramolecular Assembly

“…[ 7–9 ] Maneuvering this assembly process, organic dyes with various functionalities are expected to form intercalation into the nucleobases with tunable spatial conformation in order to control the structure–property relationships. [ 10–13 ]…”