A facile one-pot in-situ radical bulk polymerization strategy was developed for preparation of the superparamagnetic multiwalled carbon nanotubes-Fe 3 O 4 /polystyrene (CNT-Fe 3 O 4 /PS) tricomponent nanocomposite by the synergetic dispersion strategy via the multiwalled carbon nanotubes (CNT) immobilized Fe 3 O 4 nanoparticles (CNT-Fe 3 O 4 ) with oleic acid (OA) as surface modifier. Compared with the tricomponent nanocomposite prepared with the multiwalled carbon nanotubes and Fe 3 O 4 nanoparticles added separately, immobilization of Fe 3 O 4 nanoparticles on multiwalled carbon nanotubes could avoid efficiently aggregation of the Fe 3 O 4 nanoparticles in polymer matrices. OA molecules adsorb onto the surfaces of the Fe 3 O 4 nanoparticles immobilized on the multiwalled carbon nanotubes, improving efficiently the dispersibility of the multiwalled carbon nanotubes in styrene, which resulted in the well-dispersed CNT-Fe 3 O 4 /PS tricomponent nanocomposite.