We report a high mobility hole extraction material, N,N,N ,N ,-tetrakis(biphenyl-4-yl)benzidine (TBBD) for organic solar cell applications. Its highest occupied molecular orbital energy value at 5.3 eV is well matched with a donor layer and its high mobility of 1.74 × 10 −2 cm 2 /Vs brings out an easy and rapid extraction of holes from the donor material. The TBBD incorporated device showed significant improvement of opencircuit voltage, resulting in power conversion efficiency improvement of 9% compared with reference device.