“…High-temperature processing also adds considerable costs to manufacturing and increasing the energy input necessary for the process. However, highly desirable new preparation methods have been successfully elaborated at lower temperatures. − Besides the common lanthanide-doped gallogermanates M 3 Ga 2 Ge 3 O 12 − and M 3 Ga 2 Ge 4 O 14 , − M = Ca, Sr; Ln = La–Lu, Y, binary and ternary germanate crystals and nanosized crystalline compounds, such as Ca 2 GeO 4 :Ln 3+ , − In 2 Ge 2 O 7 :Ln 3+ , − LaAlGe 2 O 7 :Ln 3+ , , Y 2 CaGe 3 O 10 :Ln 3+ , and Y 2 MGe 4 O 12 :Ln 3+ , Ln = Pr–Yb, M = Ca, Mn, − have been reported for their applications in LED technologies, optical devices, and upconverting sensors. The cyclotetragermanate family Ln 2 MGe 4 O 12 (Ln = lanthanide, Y) includes compounds with two different structural types: (i) triclinic, Ln 2 CuGe 4 O 12 , space group P 1̅, Z = 1; (ii) tetragonal, Ln 2 M Ge 4 O 12 , M = Ca, Mn, Zn, space group P 4/ nbm , Z = 2 …”