In
this study, we employ direct numerical simulation (DNS) to investigate
the solutal hydrodynamics dictating the three-dimensional coalescence
of microscopic, identical-sized sessile drops of different but miscible
shear-thinning polymeric liquids (namely, PVAc or polyvinyl acetate
and PMMA or polymethylmethacrylate), with the drops being in partially
wetted configuration. Despite the ubiquitousness of the interaction
of different dissimilar droplets in a variety of engineering problems
ranging from additive manufacturing to understanding the behavior
of photonic crystals, coalescence of drops composed of different polymeric
and non-Newtonian materials has not been significantly explored. Interaction
of such dissimilar droplets often involves simultaneous drop spreading,
coalescence, and mixing. The mixing dynamics of the dissimilar drops
are governed by interphase diffusion, the residual kinetic energy
of the drops stemming from the fact that coalescence starts before
the spreading of the drops have been completed, and the solutal Marangoni
convection. We provide the three-dimensional velocity fields and velocity
vectors inside the completely miscible, dissimilar coalescing droplets.
Our simulations explicate the relative influence of these different
effects in determining the flow field at different locations and at
different time instances and the consequent mixing behavior inside
the interacting drops. We also show the non-monotonic (in terms of
the direction of migration) propagation of the mixing front of the
miscible coalescing drops over time. We also establish that the overall
mixing (on either side of the mixing front) speeds up as the Marangoni
effects dictate the mixing. We anticipate that our study will provide
an important foundation for studying miscible multi-material liquid
systems, which will be crucial for applications such as inkjet or
aerosol jet printing, lab-on-a-chip, polymer processing, etc.