As the most widely used language in the world, English has always had the largest number of learners. Therefore, this study has a practical foundation for the recognition of English stressed syllables. As is well known, listening and speaking are crucial aspects of language learning, as they are directly related to communication. Therefore, this article aimed to design a mature syllable recognition algorithm and assist it based on neural prediction models. In the end, this article used the algorithm system for a month of auxiliary training for a certain English major class, and conducted a comparative test on phrase recognition rate and pronunciation accuracy before and after. The results showed that the phrase recognition rate increased from 89.34% to 96.05%, and the pronunciation accuracy rate increased from 73.65% to 92.84%, comprehensively improving students' English learning ability.