Effects of surfactant on morphology, chemical properties and catalytic activity of hydroxyapatite

Hajimirzaee, Saeed; Chansai, Sarayute; Hardacre, Christopher; Banks, Craig E.; Doyle, Aidan M.

doi:10.1016/j.jssc.2019.05.031

Cited by 33 publications

(15 citation statements)

References 39 publications

(41 reference statements)

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“…HAP can be synthesized by various methods, including sol-gel, wet precipitation, burning in the presence of microwaves and ultrasounds [14][15][16][17][18][19][20][21]. Its slightly alkaline pH and high biocompatibility will not cause any form of secondary environmental damage.…”

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confidence: 99%

Hydroxyapatite Nanoparticles for Acidic Mine Waters Remediation

Simonescu¹,

Culiță²,

Marinescu³

et al. 2019

Rev. Chim.

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Mining activities have a high negative impact on the environment and on human health. Environmental impacts can result in contamination of surface water, groundwater, soil and air. Large volumes of wastewater produced by mining activities have to be remediated before being discharged into the environment. Due to the complex composition of wastewater coming from the mining industry and because their negative impacts, numerous remediation techniques have been applied. Adsorption is one of the most extensively used ways to remediate mining wastewater as a consequence of its low cost, easiness to be performed, and also due to the wide variety of materials (natural and synthetic) that can be use as adsorbents. Hydroxyapatite (HAP, Ca10(PO4)6(OH)2), a naturally occurring form of calcium phosphate has a good capacity to remove heavy metal ions from aqueous solutions due to its excellent properties. By preparing hydroxyapatite using different synthesis methods, its properties can be manipulated in order to increase the adsorption properties and reactivity. Herein, we reported synthesis of hydroxyapatite (HAP) samples using different synthesis conditions to establish the effect of synthesis conditions onto HAP properties. The HAP samples prepared have been characterized by the use of X-ray diffraction, FT-IR spectroscopy, specific surface measurements, Scanning Electron Microscopy (SEM). The stoichiometric compounds with high degree of crystallinity, low average particle diameter values, and low specific surface have been prepared by the solid state reaction and high calcination temepratures. The addition of surfactant (dispersant) has resulted in an increase in the specific surface area, which will result in an increase in the retention capacity of heavy metal ions in wastewater. The adsorbents prepared were used to remediate mine water. Results showed that non-calcinated HAP samples have a higher heavy metals adsorption capacity compared to HAP samples calcinated at 600 �C and 900 �C. The HAP samples prepared in presence of surfactant exhibit a higher heavy metals adsorption capacity than samples prepared in absence of surfactant. The values of the retention capacity differ depending on the nature of the metal ion: QMn(II) ] QFe(III) ] QZn(II) ] QPb(II) ] QNi(II). A change in the pH of mine water from 2.6 to 5.5 has occur that means that the metal ion retention mechanism goes through chemical reactions. The metal ions retention capacity suggests application of hydroxyapatite for remediation of mining wastewater.

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confidence: 99%

Hydroxyapatite Nanoparticles for Acidic Mine Waters Remediation

Simonescu¹,

Culiță²,

Marinescu³

et al. 2019

Rev. Chim.

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“…This means that the tested samples had, apart from recorded microporosity (pore size lower than 2 nm), also well-developed mesoporosity (pore size in the range of 2–50 nm). The isotherms presented in the figure allowed one to calculate the pore size distribution confirming their classification as the type IV [ 31 , 32 ]. Specific surface area of the samples amounted to 19.3 m 2 /g and 110.3 m 2 /g for nHAp and µHAp, respectively.…”

Section: Resultsmentioning

confidence: 99%

Micro- and Nanoparticulate Hydroxyapatite Powders as Fillers in Polyacrylate Bone Cement—A Comparative Study

Sobczyk-Guzenda¹,

Boniecka²,

Laska-Leśniewicz³

et al. 2020

Materials

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Acrylate polymer-based bone cements constitute the most popular bonding agents used in regenerative surgery. Due to their inferior biocompatibility, however, these materials are often enriched with ceramic additives including hydroxyapatite (HAp). The aim of this paper was to perform a comparative study of the acrylate cements filled with different content (3–21%) of nano- and microscale hydroxyapatite. The work concerns a comparison of times and temperatures of the cross-linking reaction, as well as morphology, glass transition temperature, and principal mechanical properties of the resulting composites. Before being used as a filler, both HAp forms were subjected to an in-depth characterization of their morphology, specific surface area, pore size distribution, and wettability as well as chemical composition and structure. For that purpose, such analytical techniques as scanning electron microscopy, Fourier-transform infrared spectroscopy, X-ray diffraction, tensiometry, Brunauer–Emmett–Teller surface area analysis, differential scanning calorimetry, Shore D hardness test, and Charpy impact test were used. The results indicated a drop of cross-linking temperature and an extension of setting time with the addition of µHAp. The µHAp-filled acrylate composites were characterized by a globular surface morphology, higher glass transition temperature, and lower hardness and impact strength compared to nHAp-filled materials. This relationship was evident at higher nHAp concentrations.

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“…In this study, hydroxyapatite particles with a Ca/P ratio of 1.7 were obtained to be a single phase by the hydrothermal method. It was considered that Ca-HAP(1.72) could be a solid solution resulting from the partial replacement of PO 4 3− ions with CO 3 2− ions [1,27]. In consequence, according to the XRD patterns, it was observed that single-phase hydroxyapatite particles were synthesized with a Ca/P molar ratio of 1.54-1.72.…”

Section: Characterizationmentioning

confidence: 99%

“…The stoichiometric form of Ca-HAP is shown as Ca 10 (PO 4 ) 6 (OH) 2 , and its Ca/P molar ratio is 1.67. However, while maintaining the single phase of apatite crystal structure, it is possible to change the Ca/P ratio ranging from 1.5 to 1.7 and substitute the constituents of Ca 2+ , PO 4 3− , and OH − with other elements to some extents [1]. Ca-HAP exhibits various unique properties, depending on changes in the chemical compositions.…”

Section: Introductionmentioning

confidence: 99%

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The Role of the Surface Acid–Base Nature of Nanocrystalline Hydroxyapatite Catalysts in the 1,6-Hexanediol Conversion

et al. 2021

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Hydroxyapatite is known to have excellent catalytic properties for ethanol conversion and lactic acid conversion, and their properties are influenced by the elemental composition, such as Ca/P ratio and sodium content. However, few reports have been examined for the surface acid–base nature of hydroxyapatites containing sodium ions. We prepared nanocrystalline hydroxyapatite (Ca-HAP) catalysts with various Ca/P ratios and sodium contents by the hydrothermal method. The adsorption and desorption experiments using NH3 and CO2 molecules and the catalytic reactions for 2-propenol conversion revealed that the surface acid–base natures changed continuously with the bulk Ca/P ratios. Furthermore, the new catalytic properties of hydroxyapatite were exhibited for 1,6-hexanediol conversion. The non-stoichiometric Ca-HAP(1.54) catalyst with sodium ions of 2.3 wt% and a Ca/P molar ratio of 1.54 gave a high 5-hexen-1-ol yield of 68%. In contrast, the Ca-HAP(1.72) catalyst, with a Ca/P molar ratio of 1.72, gave a high cyclopentanemethanol yield of 42%. Both yields were the highest ever reported in the relevant literature. It was shown that hydroxyapatite also has excellent catalytic properties for alkanediol conversion because the surface acid–base properties can be continuously controlled by the elemental compositions, such as bulk Ca/P ratios and sodium contents.

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Effects of surfactant on morphology, chemical properties and catalytic activity of hydroxyapatite

Cited by 33 publications

References 39 publications

Hydroxyapatite Nanoparticles for Acidic Mine Waters Remediation

Hydroxyapatite Nanoparticles for Acidic Mine Waters Remediation

Micro- and Nanoparticulate Hydroxyapatite Powders as Fillers in Polyacrylate Bone Cement—A Comparative Study

The Role of the Surface Acid–Base Nature of Nanocrystalline Hydroxyapatite Catalysts in the 1,6-Hexanediol Conversion

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