A two-step post-metallization annealing (PMA) process has been developed and it has demonstrated its significant benefit for high-k metal gate (HKMG) in reducing post chemical mechanical polish (CMP) Al corrosion defects.After metal gate CMP, samples are firstly treated with N 2 O plasma in a 400°C PECVD (plasma enhanced chemical vapor deposition) chamber for surface oxidization, before which the chamber has been cycled with pumping through N 2 and noble gas mixture so as to remove moisture and/or particles on chamber wall. Then, N 2 O gas switched off and NH 3 /N 2 mixture plasma turned on to nitridize the metal oxides. A multi-variable (e.g. Gas ratio, RF power, plasma treatment time, chamber pressure, etc.) statistical design of experiment (DOE) was performed to optimize processes for growing ultra-thin metal oxynitride (e.g. AlON, TiON, TaON, etc.) on top surface of the metal gate, which will work as the 2 nd etch stop layer (ESL) as well. TEM results showed that metal has been dragged upwards desirably and 30~60Å self-aligned insulated film grown upon Al/ HfO 2 capacitor, but 50~100Å diffusing layer was also observed unavoidably, which may induce metal loss and lead to a higher electrical resistance.With PMA treatment, PMOS post-CMP corrosion defects have been reduced significantly by ~85% in isolated SRAM (Static Random Access Memory), by ~50% in dense area, and by ~75% at the gate boundary area. The correlation of I OFF v.s I DSAT and I DSAT v.s V DSAT (saturation voltage at sub-threshold regime) demonstrated a comparable performance with that of non-PMA process.In light of the findings from this study, a trade-off between defect reduction and N/O atom diffusion downward metal gate should achieve with further PMA optimization.