“…In order to increase the density of interconnections, a variety of new methods/processes were developed to form solder bumps, especially the electroplating process [5,6]. However, on July 1st 2006, European Union (EU) mandated a switch to use lead-free solders in many of the electronic assembly processes because of the environmental and health considerations [1,3,5,7,8]. Accordingly, lead-free processes for electronic devices and components are profoundly required and the development of lead-free solders (e.g., Sn-Cu, Sn-Bi, Sn-Ag, Sn-Ag-Cu, Sn-Zn, etc.)…”